TY - JOUR
T1 - Selective synthesis of tetraarylgermanes and triarylgermanium halides
AU - Wolf, Melanie
AU - Falk, Astrid
AU - Flock, Michaela
AU - Torvisco Gomez, Ana
AU - Uhlig, Frank
PY - 2017/9/21
Y1 - 2017/9/21
N2 - A series of novel and previously published tetraarylgermanes aryl4Ge (aryl 1⁄4 m-tolyl, 3,4-xylyl, 3,5-xylyl, 2-naphthyl) and triarylgermanium halides aryl3GeX (aryl 1⁄4 o-tolyl, 2,4-xylyl, 2,5-xylyl, 2,6-xylyl, 1- naphthyl, 2,4,6-mesityl, X 1⁄4 Cl, Br) were synthesized and characterized. All solids were investigated using single crystal X-ray diffractometry in order to elucidate the molecular structures. Effects of the substitution pattern of the aryl residue employed have been studied in terms of the impact on the product formation.
AB - A series of novel and previously published tetraarylgermanes aryl4Ge (aryl 1⁄4 m-tolyl, 3,4-xylyl, 3,5-xylyl, 2-naphthyl) and triarylgermanium halides aryl3GeX (aryl 1⁄4 o-tolyl, 2,4-xylyl, 2,5-xylyl, 2,6-xylyl, 1- naphthyl, 2,4,6-mesityl, X 1⁄4 Cl, Br) were synthesized and characterized. All solids were investigated using single crystal X-ray diffractometry in order to elucidate the molecular structures. Effects of the substitution pattern of the aryl residue employed have been studied in terms of the impact on the product formation.
KW - Tetraarylgermanes
KW - Triarylgermanium halides
KW - Solid state structure
KW - DFT calculations
U2 - http://dx.doi.org/10.1016/j.jorganchem.2017.09.027
DO - http://dx.doi.org/10.1016/j.jorganchem.2017.09.027
M3 - Article
SN - 0022-328X
VL - 851
SP - 143
EP - 149
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
M1 - http://dx.doi.org/10.1016/j.jorganchem.2017.09.027
ER -