Selective synthesis of tetraarylgermanes and triarylgermanium halides

Melanie Wolf, Astrid Falk, Michaela Flock, Ana Torvisco Gomez, Frank Uhlig

Research output: Contribution to journalArticle

Abstract

A series of novel and previously published tetraarylgermanes aryl4Ge (aryl 1⁄4 m-tolyl, 3,4-xylyl, 3,5-xylyl, 2-naphthyl) and triarylgermanium halides aryl3GeX (aryl 1⁄4 o-tolyl, 2,4-xylyl, 2,5-xylyl, 2,6-xylyl, 1- naphthyl, 2,4,6-mesityl, X 1⁄4 Cl, Br) were synthesized and characterized. All solids were investigated using single crystal X-ray diffractometry in order to elucidate the molecular structures. Effects of the substitution pattern of the aryl residue employed have been studied in terms of the impact on the product formation.
Original languageEnglish
Article numberhttp://dx.doi.org/10.1016/j.jorganchem.2017.09.027
Pages (from-to)143-149
JournalJournal of organometallic chemistry
Volume851
DOIs
Publication statusPublished - 21 Sep 2017

Keywords

  • Tetraarylgermanes
  • Triarylgermanium halides
  • Solid state structure
  • DFT calculations

Fields of Expertise

  • Advanced Materials Science

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