Synthesis, structure and magnetic investigations of polycarboxylato-copper(II) complexes

Franz-Andreas Mautner; Jörg Albering; Ramon Vicente; Chase Andrepont; Jacob G. Gautreaux; August A. Gallo; Salah S. Massoud

doi:10.1016/j.poly.2013.02.038

Synthesis, structure and magnetic investigations of polycarboxylato-copper(II) complexes

Franz-Andreas Mautner^*, Jörg Albering, Ramon Vicente, Chase Andrepont, Jacob G. Gautreaux, August A. Gallo, Salah S. Massoud^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Polynuclear Cu(II) complexes bridged by multicarboxylate compounds (1,4,5,8-naphthalene-tetracarboxylic acid, H4nptc; 2,5-pyridinedicarboxylic acid, 2,5-H2pydc; 1,3,5-benzenetricarboxylic acid, 1,3,5-H3btc; tris(acetato)amine) have been synthesized and characterized by IR and UV–Vis spectroscopic techniques. These compounds include [Cu4(pmedien)4(μ4-nptc)(H2O)4](ClO4)4·2H2O (1), [Cu2(pmedien)2(μ2-2,5-pydc)(H2O)](ClO4)2·H2O (2), [Cu3(DPA)3(1,3,5-btc)(ClO4)3]·H2O (3), [Cu3(DPA)3(HN(CH2COO)3)(H2O)3](ClO4)4·3H2O (4), and [Cu3(pmedien)3(HN(CH2COO)3)(H2O)3](ClO4)4·2H2O (5) where pmedien = N,N,N′,N″,N″-pentamethyldiethylenetriamine and DPA = di(2-pyridymethyl)amine. X-ray single crystal crystallography reveal the tetra- and di-nulear bridging nature of the fully deprotonated acids H4nptc and 2,5-H2pydc in complexes 1 and 2, respectively. Magnetic susceptibilities of complexes 1 and 2 which were measured at variable temperatures showed very weak antiferromagnetic coupling.

Original language	English
Pages (from-to)	158-163
Journal	Polyhedron
Volume	54
DOIs	https://doi.org/10.1016/j.poly.2013.02.038
Publication status	Published - 2013

Fields of Expertise

Advanced Materials Science

Treatment code (Nähere Zuordnung)

Basic - Fundamental (Grundlagenforschung)

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10.1016/j.poly.2013.02.038

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@article{d975c6e4c7644c499f67ea684c2328e3,

title = "Synthesis, structure and magnetic investigations of polycarboxylato-copper(II) complexes",

abstract = "Polynuclear Cu(II) complexes bridged by multicarboxylate compounds (1,4,5,8-naphthalene-tetracarboxylic acid, H4nptc; 2,5-pyridinedicarboxylic acid, 2,5-H2pydc; 1,3,5-benzenetricarboxylic acid, 1,3,5-H3btc; tris(acetato)amine) have been synthesized and characterized by IR and UV–Vis spectroscopic techniques. These compounds include [Cu4(pmedien)4(μ4-nptc)(H2O)4](ClO4)4·2H2O (1), [Cu2(pmedien)2(μ2-2,5-pydc)(H2O)](ClO4)2·H2O (2), [Cu3(DPA)3(1,3,5-btc)(ClO4)3]·H2O (3), [Cu3(DPA)3(HN(CH2COO)3)(H2O)3](ClO4)4·3H2O (4), and [Cu3(pmedien)3(HN(CH2COO)3)(H2O)3](ClO4)4·2H2O (5) where pmedien = N,N,N′,N″,N″-pentamethyldiethylenetriamine and DPA = di(2-pyridymethyl)amine. X-ray single crystal crystallography reveal the tetra- and di-nulear bridging nature of the fully deprotonated acids H4nptc and 2,5-H2pydc in complexes 1 and 2, respectively. Magnetic susceptibilities of complexes 1 and 2 which were measured at variable temperatures showed very weak antiferromagnetic coupling.",

author = "Franz-Andreas Mautner and J{\"o}rg Albering and Ramon Vicente and Chase Andrepont and Gautreaux, {Jacob G.} and Gallo, {August A.} and Massoud, {Salah S.}",

year = "2013",

doi = "10.1016/j.poly.2013.02.038",

language = "English",

volume = "54",

pages = "158--163",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

}

TY - JOUR

T1 - Synthesis, structure and magnetic investigations of polycarboxylato-copper(II) complexes

AU - Mautner, Franz-Andreas

AU - Albering, Jörg

AU - Vicente, Ramon

AU - Andrepont, Chase

AU - Gautreaux, Jacob G.

AU - Gallo, August A.

AU - Massoud, Salah S.

PY - 2013

Y1 - 2013

N2 - Polynuclear Cu(II) complexes bridged by multicarboxylate compounds (1,4,5,8-naphthalene-tetracarboxylic acid, H4nptc; 2,5-pyridinedicarboxylic acid, 2,5-H2pydc; 1,3,5-benzenetricarboxylic acid, 1,3,5-H3btc; tris(acetato)amine) have been synthesized and characterized by IR and UV–Vis spectroscopic techniques. These compounds include [Cu4(pmedien)4(μ4-nptc)(H2O)4](ClO4)4·2H2O (1), [Cu2(pmedien)2(μ2-2,5-pydc)(H2O)](ClO4)2·H2O (2), [Cu3(DPA)3(1,3,5-btc)(ClO4)3]·H2O (3), [Cu3(DPA)3(HN(CH2COO)3)(H2O)3](ClO4)4·3H2O (4), and [Cu3(pmedien)3(HN(CH2COO)3)(H2O)3](ClO4)4·2H2O (5) where pmedien = N,N,N′,N″,N″-pentamethyldiethylenetriamine and DPA = di(2-pyridymethyl)amine. X-ray single crystal crystallography reveal the tetra- and di-nulear bridging nature of the fully deprotonated acids H4nptc and 2,5-H2pydc in complexes 1 and 2, respectively. Magnetic susceptibilities of complexes 1 and 2 which were measured at variable temperatures showed very weak antiferromagnetic coupling.

AB - Polynuclear Cu(II) complexes bridged by multicarboxylate compounds (1,4,5,8-naphthalene-tetracarboxylic acid, H4nptc; 2,5-pyridinedicarboxylic acid, 2,5-H2pydc; 1,3,5-benzenetricarboxylic acid, 1,3,5-H3btc; tris(acetato)amine) have been synthesized and characterized by IR and UV–Vis spectroscopic techniques. These compounds include [Cu4(pmedien)4(μ4-nptc)(H2O)4](ClO4)4·2H2O (1), [Cu2(pmedien)2(μ2-2,5-pydc)(H2O)](ClO4)2·H2O (2), [Cu3(DPA)3(1,3,5-btc)(ClO4)3]·H2O (3), [Cu3(DPA)3(HN(CH2COO)3)(H2O)3](ClO4)4·3H2O (4), and [Cu3(pmedien)3(HN(CH2COO)3)(H2O)3](ClO4)4·2H2O (5) where pmedien = N,N,N′,N″,N″-pentamethyldiethylenetriamine and DPA = di(2-pyridymethyl)amine. X-ray single crystal crystallography reveal the tetra- and di-nulear bridging nature of the fully deprotonated acids H4nptc and 2,5-H2pydc in complexes 1 and 2, respectively. Magnetic susceptibilities of complexes 1 and 2 which were measured at variable temperatures showed very weak antiferromagnetic coupling.

U2 - 10.1016/j.poly.2013.02.038

DO - 10.1016/j.poly.2013.02.038

M3 - Article

SN - 0277-5387

VL - 54

SP - 158

EP - 163

JO - Polyhedron

JF - Polyhedron

ER -

Synthesis, structure and magnetic investigations of polycarboxylato-copper(II) complexes

Abstract

Fields of Expertise

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