Differential uranyl(v) oxo-group bonding between the uranium and metal cations from groups 1, 2, 4, and 12; a high energy resolution X-ray absorption, computational, and synthetic study

Markus Zegke, Xiaobin Zhang, Ivan Pidchenko, Johann Hlina, Rianne M. Lord, Jamie Purkis, Gary S. Nichol, Nicola Magnani, Georg Schreckenbach, Tonya Vitova, Jason B. Love, Polly L. Arnold

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Uranyl Pacman takes them all: the bonding of s- and d-block cations to uranyl is compared by experiment, spectroscopy and theory.

Original languageEnglish
JournalChemical Science
DOIs
Publication statusPublished - 2019

Keywords

  • Uranium
  • Alkaline metals
  • High Energy Resolution X-ray Absorption Near Edge Structure
  • Resonant Inelastic X-ray Scattering
  • Actinide
  • Group 4 metals
  • Titanium
  • Zirconium
  • Hafnium

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