Comprehensive hazard analysis of failing automotive lithium‐ion batteries in overtemperature experiments

Christiane Essl*, Andrey W. Golubkov, Eva Gasser, Manfred Nachtnebel, Armin Zankel, Eduard Ewert, Anton Fuchs

*Corresponding author for this work

Research output: Contribution to journalArticle

Abstract

Lithium‐ion batteries (LIBs) are gaining importance in the automotive sector because of the potential of electric vehicles (EVs) to reduce greenhouse gas emissions and air pollution. However, there are serious hazards resulting from failing battery cells leading to exothermic chemical reactions inside the cell, called thermal runaway (TR). Literature of quantifying the failing behavior of modern automotive high capacity cells is rare and focusing on single hazard categories such as heat generation. Thus, the aim of this study is to quantify several hazard relevant parameters of a failing currently used battery cell extracted from a modern mass‐produced EV: The temperature response of the cell, the maximum reached cell surface temperature, the amount of produced vent gas, the gas venting rate, the composition of the produced gases including electrolyte vapor and the size and composition of the produced particles at TR. For this purpose, overtemperature experiments with fresh 41 Ah automotive lithium NMC/LMO-graphite pouch cells at different state‐of‐charge (SOC) 100%, 30% and 0% are performed. The results are valuable for firefighters, battery pack designers, cell recyclers, cell transportation and all who deal with batteries.

Original languageEnglish
Article number30
Number of pages28
JournalBatteries
Volume6
Issue number2
DOIs
Publication statusPublished - 1 Jan 2020

Keywords

  • Battery safety
  • Gas analysis
  • Hazard analysis
  • Lithium‐ion
  • Thermal runaway
  • Vent gas emission
  • Vent particle analysis

ASJC Scopus subject areas

  • Energy Engineering and Power Technology
  • Electrochemistry
  • Electrical and Electronic Engineering

Fields of Expertise

  • Advanced Materials Science

Treatment code (Nähere Zuordnung)

  • Basic - Fundamental (Grundlagenforschung)

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