Unusually selective synthesis of chlorohydrooligosilanes

Thomas Lainer, Roland Fischer, Mario Leypold, Michael Holthausen, Odo Wunnicke, Michael Haas*, Harald Stüger*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

New pathways towards molecular chlorohydrooligosilanes enable their one-pot synthesis in preparative amounts either by the selective chlorination of the corresponding perhydrosilanes with HCl/AlCl3 or by the partial hydrogenation of perchlorooligosilanes with substoichiometric amounts of iBu2AlH. The unexpected selective formation of Cl3Si-substituted species in the partial hydrogenation reactions could be related to mechanistic aspects.

Original languageEnglish
Pages (from-to)13812-13815
Number of pages4
JournalChemical Communications
Volume56
Issue number89
DOIs
Publication statusPublished - 18 Nov 2020

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Chemistry(all)
  • Catalysis

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