Thermochemical analysis and experimental investigation of a recuperative waste heat recovery system for the tri-reforming of light oil

Christian Gaber, Martin Demuth, Christoph Schluckner, Christoph Hochenauer

Research output: Contribution to journalArticleResearchpeer-review

Abstract

This paper presents a thermochemical and experimental investigation into the use of oxy-fuel exhaust gases for the tri-reforming of light oil. The thermochemical recuperation of light oil makes it possible for the furnace to burn hydrogen-rich syngas, and thereby significantly improve furnace efficiency. This study investigates three process parameters: the exhaust gas recirculation rate, the syngas temperature, and the exhaust gas temperature. (1) The more exhaust gas that is recirculated, the less oxygen is required for complete conversion into syngas, and the higher the heating value of the produced syngas. A maximum increase in the heating value of 31.6% (compared to the primary fuel) is possible if pure bi-reforming is performed. (2) The chemical equilibrium calculations showed that the syngas temperature has a strong effect on the composition of the syngas; a syngas temperature of 1265 °C is necessary to achieve a conversion rate of 99.9%. The thermodynamic analysis was performed using the Gibbs free energy minimization method. In order to prevent carbon formation, a slight oxygen excess of 1% must be present. In this case, a syngas temperature of 970 °C is sufficient for the stationary tri-reforming of light oil. (3) The energy required for reforming the primary fuel increases with increased syngas temperature, while the energy contained in the hot exhaust gas stream increases with increased exhaust gas temperature. In order to achieve a syngas temperature of at least 970 °C, both the required exhaust gas recirculation rate and the amount of oxygen for reforming and combustion are directly dependent on the temperature of the exhaust gas. An exhaust gas temperature of 1000 °C requires an exhaust gas recirculation rate of 16.2%, while a recirculation rate of 26.9% is necessary at an exhaust gas temperature of 1600 °C. In the latter case, it is possible to increase the efficiency of the oxy-fuel furnace by 22.8%.

Original languageEnglish
Pages (from-to)302-312
Number of pages11
JournalEnergy conversion and management
Volume195
DOIs
Publication statusPublished - 1 Sep 2019

Fingerprint

Waste heat utilization
Reforming reactions
Exhaust gases
Exhaust gas recirculation
Temperature
Oxygen
Furnaces
Furnace fuels
Oils
Heating
Gibbs free energy
Thermodynamics
Hydrogen
Carbon

Keywords

  • Light oil
  • Oxy-fuel combustion
  • Syngas
  • Thermochemical recuperation
  • Tri-reforming

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Fuel Technology
  • Energy Engineering and Power Technology

Cite this

Thermochemical analysis and experimental investigation of a recuperative waste heat recovery system for the tri-reforming of light oil. / Gaber, Christian; Demuth, Martin; Schluckner, Christoph; Hochenauer, Christoph.

In: Energy conversion and management, Vol. 195, 01.09.2019, p. 302-312.

Research output: Contribution to journalArticleResearchpeer-review

@article{23237aecd80d4bb6aa47a0dc0ff0e0a8,
title = "Thermochemical analysis and experimental investigation of a recuperative waste heat recovery system for the tri-reforming of light oil",
abstract = "This paper presents a thermochemical and experimental investigation into the use of oxy-fuel exhaust gases for the tri-reforming of light oil. The thermochemical recuperation of light oil makes it possible for the furnace to burn hydrogen-rich syngas, and thereby significantly improve furnace efficiency. This study investigates three process parameters: the exhaust gas recirculation rate, the syngas temperature, and the exhaust gas temperature. (1) The more exhaust gas that is recirculated, the less oxygen is required for complete conversion into syngas, and the higher the heating value of the produced syngas. A maximum increase in the heating value of 31.6{\%} (compared to the primary fuel) is possible if pure bi-reforming is performed. (2) The chemical equilibrium calculations showed that the syngas temperature has a strong effect on the composition of the syngas; a syngas temperature of 1265 °C is necessary to achieve a conversion rate of 99.9{\%}. The thermodynamic analysis was performed using the Gibbs free energy minimization method. In order to prevent carbon formation, a slight oxygen excess of 1{\%} must be present. In this case, a syngas temperature of 970 °C is sufficient for the stationary tri-reforming of light oil. (3) The energy required for reforming the primary fuel increases with increased syngas temperature, while the energy contained in the hot exhaust gas stream increases with increased exhaust gas temperature. In order to achieve a syngas temperature of at least 970 °C, both the required exhaust gas recirculation rate and the amount of oxygen for reforming and combustion are directly dependent on the temperature of the exhaust gas. An exhaust gas temperature of 1000 °C requires an exhaust gas recirculation rate of 16.2{\%}, while a recirculation rate of 26.9{\%} is necessary at an exhaust gas temperature of 1600 °C. In the latter case, it is possible to increase the efficiency of the oxy-fuel furnace by 22.8{\%}.",
keywords = "Light oil, Oxy-fuel combustion, Syngas, Thermochemical recuperation, Tri-reforming",
author = "Christian Gaber and Martin Demuth and Christoph Schluckner and Christoph Hochenauer",
year = "2019",
month = "9",
day = "1",
doi = "10.1016/j.enconman.2019.04.086",
language = "English",
volume = "195",
pages = "302--312",
journal = "Energy conversion and management",
issn = "0196-8904",
publisher = "Elsevier Limited",

}

TY - JOUR

T1 - Thermochemical analysis and experimental investigation of a recuperative waste heat recovery system for the tri-reforming of light oil

AU - Gaber, Christian

AU - Demuth, Martin

AU - Schluckner, Christoph

AU - Hochenauer, Christoph

PY - 2019/9/1

Y1 - 2019/9/1

N2 - This paper presents a thermochemical and experimental investigation into the use of oxy-fuel exhaust gases for the tri-reforming of light oil. The thermochemical recuperation of light oil makes it possible for the furnace to burn hydrogen-rich syngas, and thereby significantly improve furnace efficiency. This study investigates three process parameters: the exhaust gas recirculation rate, the syngas temperature, and the exhaust gas temperature. (1) The more exhaust gas that is recirculated, the less oxygen is required for complete conversion into syngas, and the higher the heating value of the produced syngas. A maximum increase in the heating value of 31.6% (compared to the primary fuel) is possible if pure bi-reforming is performed. (2) The chemical equilibrium calculations showed that the syngas temperature has a strong effect on the composition of the syngas; a syngas temperature of 1265 °C is necessary to achieve a conversion rate of 99.9%. The thermodynamic analysis was performed using the Gibbs free energy minimization method. In order to prevent carbon formation, a slight oxygen excess of 1% must be present. In this case, a syngas temperature of 970 °C is sufficient for the stationary tri-reforming of light oil. (3) The energy required for reforming the primary fuel increases with increased syngas temperature, while the energy contained in the hot exhaust gas stream increases with increased exhaust gas temperature. In order to achieve a syngas temperature of at least 970 °C, both the required exhaust gas recirculation rate and the amount of oxygen for reforming and combustion are directly dependent on the temperature of the exhaust gas. An exhaust gas temperature of 1000 °C requires an exhaust gas recirculation rate of 16.2%, while a recirculation rate of 26.9% is necessary at an exhaust gas temperature of 1600 °C. In the latter case, it is possible to increase the efficiency of the oxy-fuel furnace by 22.8%.

AB - This paper presents a thermochemical and experimental investigation into the use of oxy-fuel exhaust gases for the tri-reforming of light oil. The thermochemical recuperation of light oil makes it possible for the furnace to burn hydrogen-rich syngas, and thereby significantly improve furnace efficiency. This study investigates three process parameters: the exhaust gas recirculation rate, the syngas temperature, and the exhaust gas temperature. (1) The more exhaust gas that is recirculated, the less oxygen is required for complete conversion into syngas, and the higher the heating value of the produced syngas. A maximum increase in the heating value of 31.6% (compared to the primary fuel) is possible if pure bi-reforming is performed. (2) The chemical equilibrium calculations showed that the syngas temperature has a strong effect on the composition of the syngas; a syngas temperature of 1265 °C is necessary to achieve a conversion rate of 99.9%. The thermodynamic analysis was performed using the Gibbs free energy minimization method. In order to prevent carbon formation, a slight oxygen excess of 1% must be present. In this case, a syngas temperature of 970 °C is sufficient for the stationary tri-reforming of light oil. (3) The energy required for reforming the primary fuel increases with increased syngas temperature, while the energy contained in the hot exhaust gas stream increases with increased exhaust gas temperature. In order to achieve a syngas temperature of at least 970 °C, both the required exhaust gas recirculation rate and the amount of oxygen for reforming and combustion are directly dependent on the temperature of the exhaust gas. An exhaust gas temperature of 1000 °C requires an exhaust gas recirculation rate of 16.2%, while a recirculation rate of 26.9% is necessary at an exhaust gas temperature of 1600 °C. In the latter case, it is possible to increase the efficiency of the oxy-fuel furnace by 22.8%.

KW - Light oil

KW - Oxy-fuel combustion

KW - Syngas

KW - Thermochemical recuperation

KW - Tri-reforming

UR - http://www.scopus.com/inward/record.url?scp=85065392608&partnerID=8YFLogxK

U2 - 10.1016/j.enconman.2019.04.086

DO - 10.1016/j.enconman.2019.04.086

M3 - Article

VL - 195

SP - 302

EP - 312

JO - Energy conversion and management

JF - Energy conversion and management

SN - 0196-8904

ER -