Thermal-induced phase transitions in self-assembled mesostructured films studied by small-angle X-ray scattering

Plinio Innocenzi, Luca Malfatti, Tongjit Kidchob, Paolo Falcaro, Stefano Costacurta, Massimo Guglielmi, Giovanni Mattei, Valentina Bello, Heinz Amenitsch

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Two examples of phase transition in self-assembled mesostructured hybrid thin films are reported. The materials have been synthesized using tetraethoxysilane as the silica source hydrolyzed with or without the addition of methyltriethoxysilane. The combined use of transmission electron microscopy, small-angle X-ray scattering and computer simulation has been introduced to achieve a clear identification of the organized phases. A structural study of the self-assembled mesophases as a function of thermal treatment has allowed the overall phase transition to be followed. The initial symmetries of mesophases in as-deposited films have been linked to those observed in samples after thermal treatment. The monodimensional shrinkage of silica films during calcination has induced a phase transition from face-centered orthorhombic to body-centered cubic. In hybrid films, instead, the phase transition has not involved a change in the unit cell but a contraction of the cell parameter normal to the substrate.

Original languageEnglish
Pages (from-to)734-738
Number of pages5
JournalJournal of synchroton radiation
Volume12
Issue number6
DOIs
Publication statusPublished - Nov 2005
Externally publishedYes

Fingerprint

X ray scattering
Phase transitions
scattering
x rays
Heat treatment
Silica
silicon dioxide
cells
shrinkage
Calcination
roasting
contraction
computerized simulation
Transmission electron microscopy
Thin films
transmission electron microscopy
Hot Temperature
Computer simulation
symmetry
Polymers

Keywords

  • Mesoporous films
  • Phase transition
  • SAXS
  • Self-assembly

ASJC Scopus subject areas

  • Physics and Astronomy (miscellaneous)
  • Instrumentation
  • Atomic and Molecular Physics, and Optics
  • Radiation

Cite this

Thermal-induced phase transitions in self-assembled mesostructured films studied by small-angle X-ray scattering. / Innocenzi, Plinio; Malfatti, Luca; Kidchob, Tongjit; Falcaro, Paolo; Costacurta, Stefano; Guglielmi, Massimo; Mattei, Giovanni; Bello, Valentina; Amenitsch, Heinz.

In: Journal of synchroton radiation, Vol. 12, No. 6, 11.2005, p. 734-738.

Research output: Contribution to journalArticleResearchpeer-review

Innocenzi, Plinio ; Malfatti, Luca ; Kidchob, Tongjit ; Falcaro, Paolo ; Costacurta, Stefano ; Guglielmi, Massimo ; Mattei, Giovanni ; Bello, Valentina ; Amenitsch, Heinz. / Thermal-induced phase transitions in self-assembled mesostructured films studied by small-angle X-ray scattering. In: Journal of synchroton radiation. 2005 ; Vol. 12, No. 6. pp. 734-738.
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