The LiHg(22Π3/2-X2Σ1/2 +) system

Dieter Karlheinz Gruber, X. Li, Laurentius Windholz, M. M. Gleichmann, B. A. Hess, I. Vezmar, G. Pichler

Research output: Contribution to journalArticleResearchpeer-review

Abstract

We report the determination of the complete LiHg shallow bound ground state potential curve by combination of laser-induced fluorescence spectroscopy of bound-bound transitions, photoassociation spectroscopy of bound-free transitions, and ab initio calculations. The results are evaluated by comparison of quantum mechanically simulated emission spectra with experimental data and used to describe spectroscopic features of the 22Π3/2-X2Σ1/2+ band as well as the photochemical formation via excitation of the lithium dimer.

Original languageEnglish
Pages (from-to)10062-10069
Number of pages8
JournalThe Journal of Physical Chemistry
Volume100
Issue number24
Publication statusPublished - 13 Jun 1996

Fingerprint

Fluorescence spectroscopy
Lithium
Dimers
Ground state
Spectroscopy
Lasers
laser induced fluorescence
spectroscopy
emission spectra
lithium
dimers
ground state
curves
excitation

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Fields of Expertise

  • Sonstiges

Cite this

Gruber, D. K., Li, X., Windholz, L., Gleichmann, M. M., Hess, B. A., Vezmar, I., & Pichler, G. (1996). The LiHg(22Π3/2-X2Σ1/2 +) system. The Journal of Physical Chemistry, 100(24), 10062-10069.

The LiHg(22Π3/2-X2Σ1/2 +) system. / Gruber, Dieter Karlheinz; Li, X.; Windholz, Laurentius; Gleichmann, M. M.; Hess, B. A.; Vezmar, I.; Pichler, G.

In: The Journal of Physical Chemistry, Vol. 100, No. 24, 13.06.1996, p. 10062-10069.

Research output: Contribution to journalArticleResearchpeer-review

Gruber, DK, Li, X, Windholz, L, Gleichmann, MM, Hess, BA, Vezmar, I & Pichler, G 1996, 'The LiHg(22Π3/2-X2Σ1/2 +) system' The Journal of Physical Chemistry, vol. 100, no. 24, pp. 10062-10069.
Gruber DK, Li X, Windholz L, Gleichmann MM, Hess BA, Vezmar I et al. The LiHg(22Π3/2-X2Σ1/2 +) system. The Journal of Physical Chemistry. 1996 Jun 13;100(24):10062-10069.
Gruber, Dieter Karlheinz ; Li, X. ; Windholz, Laurentius ; Gleichmann, M. M. ; Hess, B. A. ; Vezmar, I. ; Pichler, G. / The LiHg(22Π3/2-X2Σ1/2 +) system. In: The Journal of Physical Chemistry. 1996 ; Vol. 100, No. 24. pp. 10062-10069.
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