The LiHg(22Π3/2-X2Σ1/2 +) system

Dieter Karlheinz Gruber, X. Li, Laurentius Windholz, M. M. Gleichmann, B. A. Hess, I. Vezmar, G. Pichler

Research output: Contribution to journalArticle

Abstract

We report the determination of the complete LiHg shallow bound ground state potential curve by combination of laser-induced fluorescence spectroscopy of bound-bound transitions, photoassociation spectroscopy of bound-free transitions, and ab initio calculations. The results are evaluated by comparison of quantum mechanically simulated emission spectra with experimental data and used to describe spectroscopic features of the 22Π3/2-X2Σ1/2+ band as well as the photochemical formation via excitation of the lithium dimer.

Original languageEnglish
Pages (from-to)10062-10069
Number of pages8
JournalThe Journal of Physical Chemistry
Volume100
Issue number24
Publication statusPublished - 13 Jun 1996

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Fields of Expertise

  • Sonstiges

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