Abstract
We report the determination of the complete LiHg shallow bound ground state potential curve by combination of laser-induced fluorescence spectroscopy of bound-bound transitions, photoassociation spectroscopy of bound-free transitions, and ab initio calculations. The results are evaluated by comparison of quantum mechanically simulated emission spectra with experimental data and used to describe spectroscopic features of the 22Π3/2-X2Σ1/2+ band as well as the photochemical formation via excitation of the lithium dimer.
Original language | English |
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Pages (from-to) | 10062-10069 |
Number of pages | 8 |
Journal | The Journal of Physical Chemistry |
Volume | 100 |
Issue number | 24 |
Publication status | Published - 13 Jun 1996 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
Fields of Expertise
- Sonstiges