The first structurally characterised oligosilylmagnesium compound

James D. Farwell, Michael F. Lappert, Christoph Marschner, Christine Strissel, T. Don Tilley

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The crystalline magnesium compounds Mg[Si(SiMe3)3]2(thf)2 (1) and MgBr[Si(SiMe3)3](thf)2 (2) are obtained in high yield from MgBr2 and the Li or K sisyl in appropriate stoichiometry in Et2O or thf; NMR spectra and X-ray crystal data for 1 and 2 confirm their structures; for 1: Mg-Si 2.682(2) Å, Si-Mg-Si′ 131.19(15)°.

Original languageEnglish
Pages (from-to)185-188
Number of pages4
JournalJournal of organometallic chemistry
Volume603
Issue number2
Publication statusPublished - 29 May 2000

Fingerprint

Magnesium Compounds
Magnesium compounds
magnesium compounds
Stoichiometry
stoichiometry
Nuclear magnetic resonance
X-Rays
Crystalline materials
X rays
nuclear magnetic resonance
Crystals
crystals
x rays
magnesium bromide

Keywords

  • A sisyl-Grignard reagent
  • Magnesium
  • Tris(trimethylsilyl)silyl ( sisyl)

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Farwell, J. D., Lappert, M. F., Marschner, C., Strissel, C., & Tilley, T. D. (2000). The first structurally characterised oligosilylmagnesium compound. Journal of organometallic chemistry, 603(2), 185-188.

The first structurally characterised oligosilylmagnesium compound. / Farwell, James D.; Lappert, Michael F.; Marschner, Christoph; Strissel, Christine; Tilley, T. Don.

In: Journal of organometallic chemistry, Vol. 603, No. 2, 29.05.2000, p. 185-188.

Research output: Contribution to journalArticleResearchpeer-review

Farwell, JD, Lappert, MF, Marschner, C, Strissel, C & Tilley, TD 2000, 'The first structurally characterised oligosilylmagnesium compound' Journal of organometallic chemistry, vol. 603, no. 2, pp. 185-188.
Farwell JD, Lappert MF, Marschner C, Strissel C, Tilley TD. The first structurally characterised oligosilylmagnesium compound. Journal of organometallic chemistry. 2000 May 29;603(2):185-188.
Farwell, James D. ; Lappert, Michael F. ; Marschner, Christoph ; Strissel, Christine ; Tilley, T. Don. / The first structurally characterised oligosilylmagnesium compound. In: Journal of organometallic chemistry. 2000 ; Vol. 603, No. 2. pp. 185-188.
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