Tetramethylammonium-calcium-triazid. Darstellung und Kristallstruktur

Translated title of the contribution: Tetramethyl ammonium calcium triazide. Preparation and crystal structure

Research output: Contribution to journalArticle

Abstract

[N(CH3)4]Ca(N3)3,M=240.29, was prepared from aqueous solutions of tetramethylammoniumazide with calciumazide at 298 K. The crystals are tetragonala=936.6(7) pm,c=694.7(5)pm, space group P4/nmm,Z=2, ρ(x)=1.31Mgm−3. The crystal structure was determined by single crystal x-ray diffraction (234 Mo-Kα-reflections, μ=0.469 mm−1,R=0.064). Calcium is octahedrally coordinated to six azide groups. The octahedra are connected via azide groups to a threedimensional array with the complex ammonium ions between. The terminal nitrogen atoms of the azide groups and the methyl groups are considerably disordered.
Translated title of the contributionTetramethyl ammonium calcium triazide. Preparation and crystal structure
Original languageGerman
Pages (from-to)1245-1249
JournalMonatshefte für Chemie - Chemical Monthly
Volume119
DOIs
Publication statusPublished - 1988

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