Chemistry of a 1,5-Oligosilanylene Dianion Containing a Disiloxane Unit

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Abstract

Synthesis of a number of disiloxane containing cyclo- and bicyclooligosilanes is described starting from the dipotassium 1,5-oligosiloxanylene diide derived from 1,3-bis[tris(trimethylsilyl)silyl]tetramethyldisiloxane. In addition, the use of this particular fragment as ligand for zinc and group 4 metallocene complexes was studied. Both types of compounds exhibit marked structural differences compared to related compounds containing Si-Si-Si units instead of the Si-O-Si fragment.
Original languageEnglish
Pages (from-to)1159-1167
Number of pages8
JournalOrganometallics
Volume38
Issue number5
DOIs
Publication statusPublished - 22 Feb 2019

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Zinc
fragments
chemistry
Ligands
zinc
ligands
synthesis
metallocene
Bistris
disiloxane

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Fields of Expertise

  • Advanced Materials Science

Cite this

Chemistry of a 1,5-Oligosilanylene Dianion Containing a Disiloxane Unit. / Zitz, Rainer; Baumgartner, Judith; Marschner, Christoph.

In: Organometallics, Vol. 38, No. 5, 22.02.2019, p. 1159-1167.

Research output: Contribution to journalArticleResearchpeer-review

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