Synthesis, structure and magnetic characterization of dinuclear copper(II) complexes of 2,6-bis[bis(pyridine-2-ylmethyl)aminomethyl]-4-methylphenol

Salah S. Massoud; Thomas Junk; Masahiro Mikuriya; Yuko Naka; Franz-Andreas Mautner

doi:10.1016/j.inoche.2014.10.027

Synthesis, structure and magnetic characterization of dinuclear copper(II) complexes of 2,6-bis[bis(pyridine-2-ylmethyl)aminomethyl]-4-methylphenol

Salah S. Massoud^*, Thomas Junk, Masahiro Mikuriya, Yuko Naka, Franz-Andreas Mautner^*

^*Corresponding author for this work

Institute of Physical and Theoretical Chemistry (6350)

Research output: Contribution to journal › Article › peer-review

Abstract

The two dinuclear complexes [Cu2(LMeO-tmpa)(OAc)2]PF6·H2O (1) and [Cu2(LMeO-tmpa)(N3)2]ClO4 (2), where LMe-OH-tmpa = 2,6-bis[bis(pyridine-2-ylmethyl)aminomethyl]-4-methylphenol, were synthesized and structurally and magnetically characterized. The five-coordinate geometry around the Cu(II) centers is achieved through the monodentate-acetato or -azido groups, the three N-donors of the ligand and a bridged-phenoxdio group. The two complexes reveal weak antiferromagnetic interaction.

Original language	English
Pages (from-to)	48-50
Journal	Inorganic Chemistry Communications
Volume	50
DOIs	https://doi.org/10.1016/j.inoche.2014.10.027
Publication status	Published - 2014

Fields of Expertise

Advanced Materials Science

Treatment code (Nähere Zuordnung)

Basic - Fundamental (Grundlagenforschung)

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10.1016/j.inoche.2014.10.027

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@article{49f2c9c57c694fb8a00ba1dbbb655008,

title = "Synthesis, structure and magnetic characterization of dinuclear copper(II) complexes of 2,6-bis[bis(pyridine-2-ylmethyl)aminomethyl]-4-methylphenol",

abstract = "The two dinuclear complexes [Cu2(LMeO-tmpa)(OAc)2]PF6·H2O (1) and [Cu2(LMeO-tmpa)(N3)2]ClO4 (2), where LMe-OH-tmpa = 2,6-bis[bis(pyridine-2-ylmethyl)aminomethyl]-4-methylphenol, were synthesized and structurally and magnetically characterized. The five-coordinate geometry around the Cu(II) centers is achieved through the monodentate-acetato or -azido groups, the three N-donors of the ligand and a bridged-phenoxdio group. The two complexes reveal weak antiferromagnetic interaction.",

author = "Massoud, {Salah S.} and Thomas Junk and Masahiro Mikuriya and Yuko Naka and Franz-Andreas Mautner",

year = "2014",

doi = "10.1016/j.inoche.2014.10.027",

language = "English",

volume = "50",

pages = "48--50",

journal = "Inorganic Chemistry Communications",

issn = "1879-0259",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Synthesis, structure and magnetic characterization of dinuclear copper(II) complexes of 2,6-bis[bis(pyridine-2-ylmethyl)aminomethyl]-4-methylphenol

AU - Massoud, Salah S.

AU - Junk, Thomas

AU - Mikuriya, Masahiro

AU - Naka, Yuko

AU - Mautner, Franz-Andreas

PY - 2014

Y1 - 2014

N2 - The two dinuclear complexes [Cu2(LMeO-tmpa)(OAc)2]PF6·H2O (1) and [Cu2(LMeO-tmpa)(N3)2]ClO4 (2), where LMe-OH-tmpa = 2,6-bis[bis(pyridine-2-ylmethyl)aminomethyl]-4-methylphenol, were synthesized and structurally and magnetically characterized. The five-coordinate geometry around the Cu(II) centers is achieved through the monodentate-acetato or -azido groups, the three N-donors of the ligand and a bridged-phenoxdio group. The two complexes reveal weak antiferromagnetic interaction.

AB - The two dinuclear complexes [Cu2(LMeO-tmpa)(OAc)2]PF6·H2O (1) and [Cu2(LMeO-tmpa)(N3)2]ClO4 (2), where LMe-OH-tmpa = 2,6-bis[bis(pyridine-2-ylmethyl)aminomethyl]-4-methylphenol, were synthesized and structurally and magnetically characterized. The five-coordinate geometry around the Cu(II) centers is achieved through the monodentate-acetato or -azido groups, the three N-donors of the ligand and a bridged-phenoxdio group. The two complexes reveal weak antiferromagnetic interaction.

U2 - 10.1016/j.inoche.2014.10.027

DO - 10.1016/j.inoche.2014.10.027

M3 - Article

SN - 1879-0259

VL - 50

SP - 48

EP - 50

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Synthesis, structure and magnetic characterization of dinuclear copper(II) complexes of 2,6-bis[bis(pyridine-2-ylmethyl)aminomethyl]-4-methylphenol

Abstract

Fields of Expertise

Treatment code (Nähere Zuordnung)

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