Synthesis, Spectroscopic Behavior, and Photoinduced Reactivity of Tetraacylgermanes

J. Radebner, M. Leypold, A. Eibel, J. Maier, L. Schuh, A. Torvisco, R. Fischer, N. Moszner, G. Gescheidt, H. Stueger, M. Haas

Research output: Contribution to journalArticle

Abstract

Acylgermanes have been subject of great interest recently because of their low toxicity and the applicability as sources for germanium-centered radicals for visible-light induced free radical polymerization processes. We report on a novel and versatile method for the synthesis of tetraacylgermanes allowing the preparation of various tetra-substituted acylgermanes 1a-m. The formation of these derivatives was confirmed by NMR spectroscopy, mass spectrometry, and X-ray crystallography. UV-vis absorption spectra of the prepared compounds reveal absorption in the visible region. This transition was assigned by TD-DFT calculations. It enabled a general screening of the influence of different substitution patterns on the absorption properties. The radical formation upon irradiation was confirmed by TR-EPR spectroscopy.
Original languageEnglish
Pages (from-to)3624-3632
JournalOrganometallics
Volume36
Issue number18
DOIs
Publication statusPublished - 2017

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