Synthesis, Characterization and Properties of bis(phenylacetylido)(tetra-phenylporphyrinato)group 14 Derivatives

Research output: Contribution to conferencePoster

Abstract

The synthesis of various porphyrinato group 14 derivatives is known from literature.[1] Such compounds are of interest due to their highly interesting electronical behavior. In case of trans-bis(phenylacetylido)(meso-tetra-phenylporphyrinato)E(IV) only the silicon derivative was known from literature so far.[2]
Here we describe the synthesis of a series of trans-bis(arylacetylido)(meso-tetra-phenylporphyrinato) group 14 derivatives and demonstrate selected properties.

[1] M. Gouterman, F. P. Schwarz, P. D. Smith, D. Dolphin, J. Chem. Phys. 1973, 59, 676-690.
[2] J. Zheng, K. Konishi, T. Aida, Inorg. Chem. 1998, 37, 2591-2594.
Original languageGerman
Publication statusPublished - 29 Aug 2016
EventInternational Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (ICCOC-GTL 2016) - Pardubice, Czech Republic
Duration: 28 Aug 20162 Sep 2016
http://www.gtl2016.cz

Conference

ConferenceInternational Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (ICCOC-GTL 2016)
CountryCzech Republic
Period28/08/162/09/16
Internet address

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