Syntheses of low-valent tin and germanium compounds with 1,3-functionalized diphosphatrisilanes

Research output: Contribution to conferencePosterResearchpeer-review

Abstract

The reaction of low-valent tin or germanium compounds with phosphanides can result in different classes of E(II)P (E = Sn, Ge) compounds. The formation of tetrylenes, rings or clusters depends not only on the reaction conditions but also on the phosphorus substituents. Due to their high reactivity and sensitivity to moisture and oxygen a very limited amount of these compounds are known so far. Especially few silicon substituted diphosphatetrylenes are known1. In the case of the cyclic derivatives no stable compound is reported yet.
Similar to their carbon analogues, the diphosphinotrisilanes are expected to offer a wide range of uses in metalorganic synthesis and complex chemistry. The few established, stable diphosphasilane derivatives are compounds of the type (R2P-SiMe2-)2.2 Other diphosphasilanes with backbone lengths of three or more silicon atoms remain, with exception of Me2Si[-Me2Si-PPh2]2,3 unexplored.
The aim of this work is the preparation of 1,3-diphosphatrisilanes, with different residues on the phosphorus, and their reactions with low-valent tin and germanium halides. The products are spectroscopically characterized and the effects of bulkiness of the substituents on the outcome of the reactions are investigated. The experimental characterization is supported by DFT calculations.
Translated title of the contributionSynthese von nieder valenten Zinn und Germanium Verbindungen mittels 1,3- funktionalisierter Diphosphatrisilane
Original languageEnglish
Publication statusPublished - 2 Sep 2019
EventInternational Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (ICCOC-GTL 2019) - Saitama University, Saitama, Japan
Duration: 1 Sep 20196 Sep 2019
http://www.chem.saitama-u.ac.jp/msaito-lab/iccoc-gtl16/

Conference

ConferenceInternational Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (ICCOC-GTL 2019)
CountryJapan
CitySaitama
Period1/09/196/09/19
Internet address

Fingerprint

Germanium compounds
Tin compounds
Silicon
Phosphorus
Germanium
Derivatives
Tin
Discrete Fourier transforms
Moisture
Carbon
Oxygen
Atoms

Cite this

Weinberger, G. P., & Flock, M. (2019). Syntheses of low-valent tin and germanium compounds with 1,3-functionalized diphosphatrisilanes. Poster session presented at International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (ICCOC-GTL 2019) , Saitama, Japan.

Syntheses of low-valent tin and germanium compounds with 1,3-functionalized diphosphatrisilanes. / Weinberger, Gernot Paul; Flock, Michaela.

2019. Poster session presented at International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (ICCOC-GTL 2019) , Saitama, Japan.

Research output: Contribution to conferencePosterResearchpeer-review

Weinberger, GP & Flock, M 2019, 'Syntheses of low-valent tin and germanium compounds with 1,3-functionalized diphosphatrisilanes' International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (ICCOC-GTL 2019) , Saitama, Japan, 1/09/19 - 6/09/19, .
Weinberger GP, Flock M. Syntheses of low-valent tin and germanium compounds with 1,3-functionalized diphosphatrisilanes. 2019. Poster session presented at International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (ICCOC-GTL 2019) , Saitama, Japan.
Weinberger, Gernot Paul ; Flock, Michaela. / Syntheses of low-valent tin and germanium compounds with 1,3-functionalized diphosphatrisilanes. Poster session presented at International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (ICCOC-GTL 2019) , Saitama, Japan.
@conference{431b6bd016094ae19411182282d11360,
title = "Syntheses of low-valent tin and germanium compounds with 1,3-functionalized diphosphatrisilanes",
abstract = "The reaction of low-valent tin or germanium compounds with phosphanides can result in different classes of E(II)P (E = Sn, Ge) compounds. The formation of tetrylenes, rings or clusters depends not only on the reaction conditions but also on the phosphorus substituents. Due to their high reactivity and sensitivity to moisture and oxygen a very limited amount of these compounds are known so far. Especially few silicon substituted diphosphatetrylenes are known1. In the case of the cyclic derivatives no stable compound is reported yet. Similar to their carbon analogues, the diphosphinotrisilanes are expected to offer a wide range of uses in metalorganic synthesis and complex chemistry. The few established, stable diphosphasilane derivatives are compounds of the type (R2P-SiMe2-)2.2 Other diphosphasilanes with backbone lengths of three or more silicon atoms remain, with exception of Me2Si[-Me2Si-PPh2]2,3 unexplored.The aim of this work is the preparation of 1,3-diphosphatrisilanes, with different residues on the phosphorus, and their reactions with low-valent tin and germanium halides. The products are spectroscopically characterized and the effects of bulkiness of the substituents on the outcome of the reactions are investigated. The experimental characterization is supported by DFT calculations.",
author = "Weinberger, {Gernot Paul} and Michaela Flock",
year = "2019",
month = "9",
day = "2",
language = "English",
note = "International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (ICCOC-GTL 2019) ; Conference date: 01-09-2019 Through 06-09-2019",
url = "http://www.chem.saitama-u.ac.jp/msaito-lab/iccoc-gtl16/",

}

TY - CONF

T1 - Syntheses of low-valent tin and germanium compounds with 1,3-functionalized diphosphatrisilanes

AU - Weinberger, Gernot Paul

AU - Flock, Michaela

PY - 2019/9/2

Y1 - 2019/9/2

N2 - The reaction of low-valent tin or germanium compounds with phosphanides can result in different classes of E(II)P (E = Sn, Ge) compounds. The formation of tetrylenes, rings or clusters depends not only on the reaction conditions but also on the phosphorus substituents. Due to their high reactivity and sensitivity to moisture and oxygen a very limited amount of these compounds are known so far. Especially few silicon substituted diphosphatetrylenes are known1. In the case of the cyclic derivatives no stable compound is reported yet. Similar to their carbon analogues, the diphosphinotrisilanes are expected to offer a wide range of uses in metalorganic synthesis and complex chemistry. The few established, stable diphosphasilane derivatives are compounds of the type (R2P-SiMe2-)2.2 Other diphosphasilanes with backbone lengths of three or more silicon atoms remain, with exception of Me2Si[-Me2Si-PPh2]2,3 unexplored.The aim of this work is the preparation of 1,3-diphosphatrisilanes, with different residues on the phosphorus, and their reactions with low-valent tin and germanium halides. The products are spectroscopically characterized and the effects of bulkiness of the substituents on the outcome of the reactions are investigated. The experimental characterization is supported by DFT calculations.

AB - The reaction of low-valent tin or germanium compounds with phosphanides can result in different classes of E(II)P (E = Sn, Ge) compounds. The formation of tetrylenes, rings or clusters depends not only on the reaction conditions but also on the phosphorus substituents. Due to their high reactivity and sensitivity to moisture and oxygen a very limited amount of these compounds are known so far. Especially few silicon substituted diphosphatetrylenes are known1. In the case of the cyclic derivatives no stable compound is reported yet. Similar to their carbon analogues, the diphosphinotrisilanes are expected to offer a wide range of uses in metalorganic synthesis and complex chemistry. The few established, stable diphosphasilane derivatives are compounds of the type (R2P-SiMe2-)2.2 Other diphosphasilanes with backbone lengths of three or more silicon atoms remain, with exception of Me2Si[-Me2Si-PPh2]2,3 unexplored.The aim of this work is the preparation of 1,3-diphosphatrisilanes, with different residues on the phosphorus, and their reactions with low-valent tin and germanium halides. The products are spectroscopically characterized and the effects of bulkiness of the substituents on the outcome of the reactions are investigated. The experimental characterization is supported by DFT calculations.

M3 - Poster

ER -