Structural characterization of ferromagnetic bridged-acetato and -dichlorido copper(II) complexes based on bicompartmental 4-t-butylphenol

Salah S. Massoud, Thomas Junk, Radovan Herchel, Zdenek Travnicek, Masahiro Mikuriya, Roland C. Fischer, Franz A. Mautner

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The reaction of Cu(II) salts with 2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-t-butylphenol (Lt-Bu-OH) afforded two bridged-phenoxido/hydroxido complexes. The dinuclear bridged acetate species [Cu2(μ-Lt-Bu-O)(μ-CH3COO)](PF6)2 (1) and the 1D polymeric doubly-bridged-chlorido {[Cu2(μ-Lt-Bu-OH)(μ-Cl)2](ClO4)2·4H2O}n (2). The two complexes were structurally characterized. Both complexes revealed ferromagnetic interactions; moderate in complex 1 (J = + 30.8 cm- 1) and very weak (J = + 2.25 cm-1) in 2. [on SciFinder(R)]
Original languageEnglish
Pages (from-to)1-3
Number of pages3
JournalInorganic chemistry communications
Volume60
DOIs
Publication statusPublished - 2015

Keywords

    Fields of Expertise

    • Advanced Materials Science

    Treatment code (Nähere Zuordnung)

    • Basic - Fundamental (Grundlagenforschung)

    Cite this

    Structural characterization of ferromagnetic bridged-acetato and -dichlorido copper(II) complexes based on bicompartmental 4-t-butylphenol. / Massoud, Salah S.; Junk, Thomas; Herchel, Radovan; Travnicek, Zdenek; Mikuriya, Masahiro; Fischer, Roland C.; Mautner, Franz A.

    In: Inorganic chemistry communications, Vol. 60, 2015, p. 1-3.

    Research output: Contribution to journalArticleResearchpeer-review

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    title = "Structural characterization of ferromagnetic bridged-acetato and -dichlorido copper(II) complexes based on bicompartmental 4-t-butylphenol",
    abstract = "The reaction of Cu(II) salts with 2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-t-butylphenol (Lt-Bu-OH) afforded two bridged-phenoxido/hydroxido complexes. The dinuclear bridged acetate species [Cu2(μ-Lt-Bu-O)(μ-CH3COO)](PF6)2 (1) and the 1D polymeric doubly-bridged-chlorido {[Cu2(μ-Lt-Bu-OH)(μ-Cl)2](ClO4)2·4H2O}n (2). The two complexes were structurally characterized. Both complexes revealed ferromagnetic interactions; moderate in complex 1 (J = + 30.8 cm- 1) and very weak (J = + 2.25 cm-1) in 2. [on SciFinder(R)]",
    keywords = "prepn crystal structure copper pyridylmethylaminomethylbutylphenol complex, magnetic property copper pyridylmethylaminomethylbutylphenol complex",
    author = "Massoud, {Salah S.} and Thomas Junk and Radovan Herchel and Zdenek Travnicek and Masahiro Mikuriya and Fischer, {Roland C.} and Mautner, {Franz A.}",
    note = "M1 - Copyright (C) 2017 American Chemical Society (ACS). All Rights Reserved. CAPLUS AN 2015:1248780(Journal; Online Computer File)",
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    doi = "10.1016/j.inoche.2015.07.010",
    language = "English",
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    T1 - Structural characterization of ferromagnetic bridged-acetato and -dichlorido copper(II) complexes based on bicompartmental 4-t-butylphenol

    AU - Massoud, Salah S.

    AU - Junk, Thomas

    AU - Herchel, Radovan

    AU - Travnicek, Zdenek

    AU - Mikuriya, Masahiro

    AU - Fischer, Roland C.

    AU - Mautner, Franz A.

    N1 - M1 - Copyright (C) 2017 American Chemical Society (ACS). All Rights Reserved. CAPLUS AN 2015:1248780(Journal; Online Computer File)

    PY - 2015

    Y1 - 2015

    N2 - The reaction of Cu(II) salts with 2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-t-butylphenol (Lt-Bu-OH) afforded two bridged-phenoxido/hydroxido complexes. The dinuclear bridged acetate species [Cu2(μ-Lt-Bu-O)(μ-CH3COO)](PF6)2 (1) and the 1D polymeric doubly-bridged-chlorido {[Cu2(μ-Lt-Bu-OH)(μ-Cl)2](ClO4)2·4H2O}n (2). The two complexes were structurally characterized. Both complexes revealed ferromagnetic interactions; moderate in complex 1 (J = + 30.8 cm- 1) and very weak (J = + 2.25 cm-1) in 2. [on SciFinder(R)]

    AB - The reaction of Cu(II) salts with 2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-t-butylphenol (Lt-Bu-OH) afforded two bridged-phenoxido/hydroxido complexes. The dinuclear bridged acetate species [Cu2(μ-Lt-Bu-O)(μ-CH3COO)](PF6)2 (1) and the 1D polymeric doubly-bridged-chlorido {[Cu2(μ-Lt-Bu-OH)(μ-Cl)2](ClO4)2·4H2O}n (2). The two complexes were structurally characterized. Both complexes revealed ferromagnetic interactions; moderate in complex 1 (J = + 30.8 cm- 1) and very weak (J = + 2.25 cm-1) in 2. [on SciFinder(R)]

    KW - prepn crystal structure copper pyridylmethylaminomethylbutylphenol complex

    KW - magnetic property copper pyridylmethylaminomethylbutylphenol complex

    U2 - 10.1016/j.inoche.2015.07.010

    DO - 10.1016/j.inoche.2015.07.010

    M3 - Article

    VL - 60

    SP - 1

    EP - 3

    JO - Inorganic chemistry communications

    JF - Inorganic chemistry communications

    SN - 1387-7003

    ER -