Structural characterization of μ1,2- and μ1,3-bridged-squarato 1D metal(II) coordination polymers.

Franz A. Mautner; Roland C. Fischer; Masahiro Mikuriya; Seiki Tomohara; Lauren M. Deniger; Salah S. Massoud

doi:10.1016/j.poly.2015.07.073

Structural characterization of μ1,2- and μ1,3-bridged-squarato 1D metal(II) coordination polymers.

Franz A. Mautner, Roland C. Fischer, Masahiro Mikuriya, Seiki Tomohara, Lauren M. Deniger, Salah S. Massoud

Research output: Contribution to journal › Article › peer-review

Abstract

Three bridged squarato 1-dimensional polymeric M(II) complexes were synthesized and structurally characterized: {[Cu2(LBDPA)(μ1,2-C4O4)(H2O)](ClO4)2·2H2O}n (1), {[Mn(DPA)(μ1,2-C4O4)(H2O)]·2H2O}n (2) and {[Zn(DPA)(μ1,3-C4O4)(H2O)]·2H2O}n (3) where LBDPA = 2,6-bis[bis(2-pyridylmethyl)aminomethyl]pyridine (LBDPA), DPA = bis(2-pyridylmethyl)amine, C4O2-4 = squarate dianion. Also, attempts were made to solve the x-ray structure of [Cd(Mepea)(μ1,2-C4O4)(H2O)]n (4) (Mepea = N-methyl-(2-pyridylmethyl)-(2-(2-pyridyl)ethyl)amine). The C4O2-4 dianions are bridging the M2+ centers via bis(monodentate) μ1,2-(cis) or μ1,3-(trans) bonding modes. Complex 1 reveals very weak antiferromagnetic coupling between the Cu(II) ions. [on SciFinder(R)]

Original language	English
Pages (from-to)	82-87
Number of pages	6
Journal	Polyhedron
Volume	102
DOIs	https://doi.org/10.1016/j.poly.2015.07.073
Publication status	Published - 2015

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10.1016/j.poly.2015.07.073

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@article{9bcf4caa291c41dd9ed6214318a32150,

title = "Structural characterization of μ1,2- and μ1,3-bridged-squarato 1D metal(II) coordination polymers.",

abstract = "Three bridged squarato 1-dimensional polymeric M(II) complexes were synthesized and structurally characterized: {[Cu2(LBDPA)(μ1,2-C4O4)(H2O)](ClO4)2·2H2O}n (1), {[Mn(DPA)(μ1,2-C4O4)(H2O)]·2H2O}n (2) and {[Zn(DPA)(μ1,3-C4O4)(H2O)]·2H2O}n (3) where LBDPA = 2,6-bis[bis(2-pyridylmethyl)aminomethyl]pyridine (LBDPA), DPA = bis(2-pyridylmethyl)amine, C4O2-4 = squarate dianion. Also, attempts were made to solve the x-ray structure of [Cd(Mepea)(μ1,2-C4O4)(H2O)]n (4) (Mepea = N-methyl-(2-pyridylmethyl)-(2-(2-pyridyl)ethyl)amine). The C4O2-4 dianions are bridging the M2+ centers via bis(monodentate) μ1,2-(cis) or μ1,3-(trans) bonding modes. Complex 1 reveals very weak antiferromagnetic coupling between the Cu(II) ions. [on SciFinder(R)]",

keywords = "prepn transition metal squarate pyridylmethylamine coordination polymer, crystal structure transition metal squarate pyridylmethylamine coordination polymer, magnetic property transition metal squarate pyridylmethylamine coordination polymer",

author = "Mautner, {Franz A.} and Fischer, {Roland C.} and Masahiro Mikuriya and Seiki Tomohara and Deniger, {Lauren M.} and Massoud, {Salah S.}",

year = "2015",

doi = "10.1016/j.poly.2015.07.073",

language = "English",

volume = "102",

pages = "82--87",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

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T1 - Structural characterization of μ1,2- and μ1,3-bridged-squarato 1D metal(II) coordination polymers.

AU - Mautner, Franz A.

AU - Fischer, Roland C.

AU - Mikuriya, Masahiro

AU - Tomohara, Seiki

AU - Deniger, Lauren M.

AU - Massoud, Salah S.

PY - 2015

Y1 - 2015

N2 - Three bridged squarato 1-dimensional polymeric M(II) complexes were synthesized and structurally characterized: {[Cu2(LBDPA)(μ1,2-C4O4)(H2O)](ClO4)2·2H2O}n (1), {[Mn(DPA)(μ1,2-C4O4)(H2O)]·2H2O}n (2) and {[Zn(DPA)(μ1,3-C4O4)(H2O)]·2H2O}n (3) where LBDPA = 2,6-bis[bis(2-pyridylmethyl)aminomethyl]pyridine (LBDPA), DPA = bis(2-pyridylmethyl)amine, C4O2-4 = squarate dianion. Also, attempts were made to solve the x-ray structure of [Cd(Mepea)(μ1,2-C4O4)(H2O)]n (4) (Mepea = N-methyl-(2-pyridylmethyl)-(2-(2-pyridyl)ethyl)amine). The C4O2-4 dianions are bridging the M2+ centers via bis(monodentate) μ1,2-(cis) or μ1,3-(trans) bonding modes. Complex 1 reveals very weak antiferromagnetic coupling between the Cu(II) ions. [on SciFinder(R)]

AB - Three bridged squarato 1-dimensional polymeric M(II) complexes were synthesized and structurally characterized: {[Cu2(LBDPA)(μ1,2-C4O4)(H2O)](ClO4)2·2H2O}n (1), {[Mn(DPA)(μ1,2-C4O4)(H2O)]·2H2O}n (2) and {[Zn(DPA)(μ1,3-C4O4)(H2O)]·2H2O}n (3) where LBDPA = 2,6-bis[bis(2-pyridylmethyl)aminomethyl]pyridine (LBDPA), DPA = bis(2-pyridylmethyl)amine, C4O2-4 = squarate dianion. Also, attempts were made to solve the x-ray structure of [Cd(Mepea)(μ1,2-C4O4)(H2O)]n (4) (Mepea = N-methyl-(2-pyridylmethyl)-(2-(2-pyridyl)ethyl)amine). The C4O2-4 dianions are bridging the M2+ centers via bis(monodentate) μ1,2-(cis) or μ1,3-(trans) bonding modes. Complex 1 reveals very weak antiferromagnetic coupling between the Cu(II) ions. [on SciFinder(R)]

KW - prepn transition metal squarate pyridylmethylamine coordination polymer

KW - crystal structure transition metal squarate pyridylmethylamine coordination polymer

KW - magnetic property transition metal squarate pyridylmethylamine coordination polymer

U2 - 10.1016/j.poly.2015.07.073

DO - 10.1016/j.poly.2015.07.073

M3 - Article

SN - 0277-5387

VL - 102

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EP - 87

JO - Polyhedron

JF - Polyhedron

ER -