Silole Allylic Anions Instead of Silanides

Alexander Pöcheim; Lena Albers; Thomas  Müller; Judith Baumgartner; Christoph Marschner

doi:10.1039/D1DT02363B

Silole Allylic Anions Instead of Silanides

Alexander Pöcheim, Lena Albers, Thomas Müller, Judith Baumgartner^*, Christoph Marschner^*

^*Corresponding author for this work

Institute of Inorganic Chemistry (6330)

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of a 3,4-diphenylsilole with two neopentasilanyl groups attached to the 2- and 5-positions with one equivalent of KOtBu did not result in the expected silanide formation but yielded a silole allylic anion instead. The initially formed silanide added to a neighbouring phenyl group, which then transfers a proton to the 2-position of the silole ring

Original language	English
Pages (from-to)	16945–16949
Number of pages	5
Journal	Dalton Transactions
Volume	50
DOIs	https://doi.org/10.1039/D1DT02363B
Publication status	Published - 14 Dec 2021

Fields of Expertise

Advanced Materials Science

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10.1039/D1DT02363BLicence: CC BY 4.0

Cite this

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title = "Silole Allylic Anions Instead of Silanides",

abstract = "Reaction of a 3,4-diphenylsilole with two neopentasilanyl groups attached to the 2- and 5-positions with one equivalent of KOtBu did not result in the expected silanide formation but yielded a silole allylic anion instead. The initially formed silanide added to a neighbouring phenyl group, which then transfers a proton to the 2-position of the silole ring",

author = "Alexander P{\"o}cheim and Lena Albers and Thomas M{\"u}ller and Judith Baumgartner and Christoph Marschner",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2021",

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day = "14",

doi = "10.1039/D1DT02363B",

language = "English",

volume = "50",

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journal = "Dalton Transactions",

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T1 - Silole Allylic Anions Instead of Silanides

AU - Pöcheim, Alexander

AU - Albers, Lena

AU - Müller, Thomas

AU - Baumgartner, Judith

AU - Marschner, Christoph

PY - 2021/12/14

Y1 - 2021/12/14

N2 - Reaction of a 3,4-diphenylsilole with two neopentasilanyl groups attached to the 2- and 5-positions with one equivalent of KOtBu did not result in the expected silanide formation but yielded a silole allylic anion instead. The initially formed silanide added to a neighbouring phenyl group, which then transfers a proton to the 2-position of the silole ring

AB - Reaction of a 3,4-diphenylsilole with two neopentasilanyl groups attached to the 2- and 5-positions with one equivalent of KOtBu did not result in the expected silanide formation but yielded a silole allylic anion instead. The initially formed silanide added to a neighbouring phenyl group, which then transfers a proton to the 2-position of the silole ring

UR - http://www.scopus.com/inward/record.url?scp=85120675690&partnerID=8YFLogxK

U2 - 10.1039/D1DT02363B

DO - 10.1039/D1DT02363B

M3 - Article

SN - 1477-9226

VL - 50

SP - 16945

EP - 16949

JO - Dalton Transactions

JF - Dalton Transactions

ER -

Silole Allylic Anions Instead of Silanides

Abstract

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