Abstract
The reaction of dibutyl disulfide with bromine readily yields butylsulfenyl bromide at room temperature. Electrophilic addition of butylsulfenyl bromide to olefins leads rapidly to the formation of the corresponding α-bromo, β-butylthio derivative under mild conditions. The applicability of this reagent for the efficient postpolymerization modification of unsaturated polyolefins is demonstrated.
Original language | English |
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Pages (from-to) | 5557-5560 |
Journal | Polymer |
Volume | 55 |
Issue number | 22 |
DOIs | |
Publication status | Published - 2014 |
Treatment code (Nähere Zuordnung)
- Basic - Fundamental (Grundlagenforschung)