Redistribution reaction on a six-fold coordinated Sn(IV) atom and reactions towards axially unsymmetric substituted Sn(IV) porphyrins

Doris Martina Grössl (Guest editor), Stefan Stadlbauer*, Roland Fischer (Guest editor), Frank Uhlig, Nicola Demitri (Guest editor)

*Corresponding author for this work

Research output: Contribution to journalArticle

Abstract

Investigations of the Kocheshkov redistribution reaction were performed on the six fold coordinated tin(IV) atom using the axially coordinated Sn(IV) meso-tetra-phenylporphyrin system with axially trans di-chloro and trans di-acetylido substituted derivatives. The immobile four dentate porphyrin ligand enables the detailed investigation of these typically complex reaction systems on higher coordinated tin(IV) species. The thermally activated reaction displays an equilibrium. Further on, a series of axial unsymmetrically substituted Sn(IV) porphyrins are selectively synthesized and described.

Original languageEnglish
Article number121470
JournalJournal of Organometallic Chemistry
Volume925
DOIs
Publication statusPublished - 15 Oct 2020

Keywords

  • Axially asymmetric substituted Sn(IV) porphyrin
  • Kocheshkov
  • Redistribution reaction

ASJC Scopus subject areas

  • Materials Chemistry
  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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