Probing the first steps of photoinduced free radical polymerization at water-oil interfaces

Denisa Darvasiová, Zuzana Barberiková, Anna Eibel, Max Schmallegger, Georg Gescheidt, Michal Zalibera, Dmytro Neshchadin

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Phosphanoyl radicals, produced by α-photocleavage of exclusively octane-soluble acylphosphane oxides, rapidly react with both water- and octane-soluble monomers in water-in-octane microemulsions. The presented mechanistic insights open the possibility for the tailored construction of photo-generated copolymers comprising polar and non-polar blocks at the same time.

Original languageEnglish
Pages (from-to)6943-6947
Number of pages5
JournalPolymer Chemistry
Volume8
Issue number45
DOIs
Publication statusPublished - 7 Dec 2017

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Free radical polymerization
Polymerization
Free Radicals
Oils
Water
Microemulsions
Copolymers
Monomers
Oxides
octane

ASJC Scopus subject areas

  • Bioengineering
  • Biochemistry
  • Polymers and Plastics
  • Organic Chemistry

Cite this

Probing the first steps of photoinduced free radical polymerization at water-oil interfaces. / Darvasiová, Denisa; Barberiková, Zuzana; Eibel, Anna; Schmallegger, Max; Gescheidt, Georg; Zalibera, Michal; Neshchadin, Dmytro.

In: Polymer Chemistry, Vol. 8, No. 45, 07.12.2017, p. 6943-6947.

Research output: Contribution to journalArticleResearchpeer-review

Darvasiová, Denisa ; Barberiková, Zuzana ; Eibel, Anna ; Schmallegger, Max ; Gescheidt, Georg ; Zalibera, Michal ; Neshchadin, Dmytro. / Probing the first steps of photoinduced free radical polymerization at water-oil interfaces. In: Polymer Chemistry. 2017 ; Vol. 8, No. 45. pp. 6943-6947.
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