Postsynthetic Metalated MOFs as Atomically Dispersed Catalysts for Hydroformylation Reactions

Panjuan Tang, Stefano Paganelli, Francesco Carraro*, Matias Blanco, Raffaele Riccò, Carla Marega, Denis Badocco, Paolo Pastore, Christian J. Doonan, Stefano Agnoli*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

A manganese-based metal-organic framework with dipyrazole ligands has been metalated with atomically dispersed Rh and Co species and used as a catalyst for the hydroformylation of styrene. The Rh-based materials exhibited excellent conversion at 80 °C with complete chemoselectivity, high selectivity for the branched aldehyde, high recyclability, and negligible metal leaching.

Original languageEnglish
Pages (from-to)54798-54805
Number of pages8
JournalACS Applied Materials and Interfaces
Volume12
Issue number49
DOIs
Publication statusPublished - 9 Dec 2020

Keywords

  • heterogeneous catalysis
  • hydroformylation of olefins
  • metal-organic frameworks
  • rhodium coordination compounds
  • single-atom catalysts

ASJC Scopus subject areas

  • Materials Science(all)

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