Dense thin-film microelectrodes of the first-order Ruddlesden-Popper phases Pr2NiO4+δ (PNO) and Pr2Ni0.9Co0.1O4+δ (PNCO) were prepared by pulsed laser deposition and photolithographic patterning on yttria-stabilized zirconia (YSZ) substrates. The thin-films were characterized by X-ray diffraction, scanning electron microscopy, scanning transmission electron microscopy, inductively coupled plasma optical emission spectroscopy, energy dispersive X-ray spectroscopy and electron energy loss spectroscopy. Investigation of the phase stability of PNO and its reactivity with YSZ was performed by X-ray diffraction analyses after high-temperature treatment in air. Resistive and capacitive contributions of the individual processes occurring at the microelectrodes were determined by means of electrochemical impedance spectroscopy at various temperatures (550 ≤ T/°C ≤ 850) and oxygen partial pressures (1 × 10−3 ≤ pO2/bar ≤ 1). Oxygen surface exchange coefficients kq and kchem were calculated from the surface resistances and chemical capacitances of the thin-film electrodes. Comparing kq-values of PNO and PNCO shows that substitution of Ni with 10% of Co increases the oxygen surface exchange rates, especially at lower oxygen partial pressures.
ASJC Scopus subject areas
- Materials Science(all)
Fields of Expertise
- Advanced Materials Science
Treatment code (Nähere Zuordnung)
- Basic - Fundamental (Grundlagenforschung)
Berger, C., Egger, A., Merkle, R., Bucher, E., Stuhlhofer, B., Schrödl, N., ... Sitte, W. (2019). Oxygen Surface Exchange Kinetics of Pr2(Ni,Co)O4+δ Thin-FilmModel Electrodes. Journal of the Electrochemical Society, 166(14), F1088-F1095. https://doi.org/10.1149/2.0521914jes