TY - JOUR
T1 - Origin of high electromechanical properties in (K,Na)NbO3 -based lead-free piezoelectrics modified with BaZr O3
AU - Zhang, Mao Hua
AU - Liu, Yi Xuan
AU - Wang, Ke
AU - Koruza, Jurij
AU - Schultheiß, Jan
N1 - Funding Information:
This work was partially supported by the Deutsche Forschungsgemeinschaft (DFG) under Grant No. 270195408 (KO5100/1-1). K.W. acknowledges the support of the National Nature Science Foundation of China (Grants No. 51822206 and No. 51761135118). J.S. acknowledges the support of the Feodor Lynen Research Fellowship Program of the Alexander von Humboldt Foundation. Patrick Breckner is acknowledged for writing the image processing program for grain-size analysis.
Publisher Copyright:
© 2020 American Physical Society.
PY - 2020/6
Y1 - 2020/6
N2 - After two decades of extensive research, selected lead-free piezoelectric materials based on the (K,Na)NbO3 (KNN) system exhibit excellent electromechanical properties that are comparable or even superior to those of Pb(Zr,Ti)O3. The origin of the superior properties, however, remains insufficiently understood. Here, we establish a correlation between electromechanical properties and domain-wall dynamics for a prominent piezoceramic (K,Na)NbO3-based composition, modified with (Bi0.5Li0.5)TiO3 and different amounts of BaZrO3. This composition combines excellent piezoelectric properties, high fatigue resistance, and low leakage currents. Domain-wall dynamics were studied over a broad range of electric fields, combining subcoercive field and dynamic pulse measurements. We find that the enhanced electromechanical properties in these materials are caused by easier domain-wall movement. Besides providing insights into fundamental mechanisms of domain-wall dynamics in KNN-based materials, our results can serve as a future guidance for the design of high-performance KNN compositions.
AB - After two decades of extensive research, selected lead-free piezoelectric materials based on the (K,Na)NbO3 (KNN) system exhibit excellent electromechanical properties that are comparable or even superior to those of Pb(Zr,Ti)O3. The origin of the superior properties, however, remains insufficiently understood. Here, we establish a correlation between electromechanical properties and domain-wall dynamics for a prominent piezoceramic (K,Na)NbO3-based composition, modified with (Bi0.5Li0.5)TiO3 and different amounts of BaZrO3. This composition combines excellent piezoelectric properties, high fatigue resistance, and low leakage currents. Domain-wall dynamics were studied over a broad range of electric fields, combining subcoercive field and dynamic pulse measurements. We find that the enhanced electromechanical properties in these materials are caused by easier domain-wall movement. Besides providing insights into fundamental mechanisms of domain-wall dynamics in KNN-based materials, our results can serve as a future guidance for the design of high-performance KNN compositions.
UR - http://www.scopus.com/inward/record.url?scp=85088531580&partnerID=8YFLogxK
U2 - 10.1103/PhysRevMaterials.4.064407
DO - 10.1103/PhysRevMaterials.4.064407
M3 - Article
AN - SCOPUS:85088531580
SN - 2475-9953
VL - 4
JO - Physical Review Materials
JF - Physical Review Materials
IS - 6
M1 - 064407
ER -