Novel diaminopropyl substituted organotin compounds

Research output: Contribution to journalArticle

Abstract

A novel synthetic pathway involving the desilylation of a tin trimethylsilyl species (Ph2Sn(SiMe3)2) towards nonprotected di(3-aminopropyl)tin dichloride ((H2N(CH2)3)2SnCl2) is described. Di(3-aminopropyl)tin dichloride is then converted to the respective dicarboxylates species (H2N(CH2)3)2Sn(OCOR)2 containing carboxylic acids of different lengths (R = –CH3, –(CH2)10CH3). Depending on the nature of R, discrete packing effects are observed in the solid state of di(3-aminopropyl)tin dicarboxylate derivatives. All the synthesized substances were characterized by 1H, 13C, and 119Sn nuclear magnetic resonance data and also single crystal X-ray analysis. These compounds are a promising class of substances for biological, pharmaceutical, and technical applications.
Original languageEnglish
Pages (from-to)411
Number of pages418
JournalCanadian Journal of Chemistry
Volume96
Issue number4
DOIs
Publication statusPublished - 8 Feb 2018

Keywords

  • organotin
  • diaminopropyl
  • 119Sn NMR
  • single crystal X-ray diffraction
  • crystal packing motifs

Fields of Expertise

  • Advanced Materials Science

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