New insights into the selective and systematic preparation of arylgermanium hydrides

Ana Torvisco Gomez*, Melanie Wolf, Michael Traxler, Dietrich Gudat, Frank Uhlig

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

A series of novel arylgermanium hydrides Ar nGeH 4 –n (n = 1–3) and diaryl(chloro)germanium hydrides Ar 2Ge(Cl)H were synthesized and characterized. Systematic preparation and purification were achieved via the lithium chloride–triflic acid and the optimized Grignard route. Arylgermanium hydrides ArnGeH 4– n (Ar = 2,5-Me 2C 6H 3, n = 1–3) were characterized by 1H and 73Ge NMR spectroscopy and single crystal X-ray diffractometry.

Original languageEnglish
Pages (from-to)22-24
Number of pages3
JournalMendeleev Communications
Volume32
Issue number1
DOIs
Publication statusPublished - Jan 2022

Keywords

  • arylgermanium hydrides
  • 73Ge NMR spectroscopy
  • H NMR spectroscopy
  • aryl(chloro)germanium hydrides
  • organogermanium compounds
  • solid-state structures
  • Ge NMR spectroscopy

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Chemistry(all)

Fields of Expertise

  • Advanced Materials Science

Fingerprint

Dive into the research topics of 'New insights into the selective and systematic preparation of arylgermanium hydrides'. Together they form a unique fingerprint.

Cite this