Modeling of Single Droplet Mass Transfer of Acetic Acid with Triisooctylamine-Based Solvent

Georg Rudelstorfer*, Matthäus Siebenhofer, Annika Grafschafter

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The design of mass transfer equipment based on single droplet mass transfer data is still a great challenge, although having been subject of intensive discussion for decades already. Extraction with chemical reaction may rather contribute to additional problems when modeling single droplet mass transfer. Single droplet mass transfer of acetic acid from aqueous carrier into triisooctylamine based solvents modified with the Lewis acid modifier isodecanol and the diluent Shellsol T has been investigated. Mass transfer of acetic acid into triisooctylamine-based solvent droplets is strictly controlled (actually limited) by diffusion of the laden solvent from the interface into the droplet bulk phase.

Original languageEnglish
Pages (from-to)1509-1517
Number of pages9
JournalChemie-Ingenieur-Technik
Volume93
Issue number10
DOIs
Publication statusPublished - Oct 2021

Keywords

  • Acetic acid extraction
  • Amine-based solvents
  • Liquid-liquid extraction
  • Mass transfer
  • Single droplet

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)
  • Industrial and Manufacturing Engineering

Fields of Expertise

  • Sustainable Systems

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