Abstract
The solvent absorption of an epoxy o-cresol novolac resin composite has been measured in different aqueous electrolyte solutions (NaCl, CaCl2 and MgCl2) at different salt concentrations from 0.1 to 0.3 mg/l. Next to the total solvent uptake, which was measured by a gravimetric measurement, the absorption of ions was determined by ion chromatography and by atomic absorption spectroscopy. The measured solvent absorption in equilibrium was calculated by combining the ePC-SAFT equation of state with a network term, which takes into account elastic forces in the polymer network counteracting a further solvent absorption. In order to model the solvent absorption kinetics, the equation of state was combined with a Maxwell-Stefan diffusion approach and the viscoelastic Kelvin-Voigt model for chain relaxation. The model parameters were only fitted to the absorption in pure water, what was only possible because the epoxy resin absorbed a neglectable amount of ions. The fully predictively calculated values for the absorption in electrolyte solutions are in qualitative agreement to the measured data.
Original language | English |
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Article number | 112881 |
Journal | Fluid Phase Equilibria |
Volume | 529 |
DOIs | |
Publication status | Published - 1 Feb 2021 |
Keywords
- Electrolytes
- Maxwell-Stefan Diffusion
- PC-SAFT
- Polymer Thermodynamics
- Swelling
ASJC Scopus subject areas
- Chemical Engineering(all)
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry