Abstract
Abstract: Mesoporous nanocrystalline TiO2 and TiO2–V2O5 microspheres were prepared by non-hydrolytic sol–gel from TiCl4, VOCl3, and iPr2O at 110 °C without any solvent or additives. The samples were characterized by elemental analysis, X-ray diffraction, Raman spectroscopy, scanning electron microscopy, nitrogen physisorption, and impedance measurements. At low vanadium loadings, only TiO2 anatase was detected, and V2O5 scherbinaite was also detected at high vanadium loadings. The texture of the samples depended on the V loading, but all the samples appeared built of primary nanoparticles (≈10–20 nm in size) that aggregate to form mesoporous micron-sized spheres. The lithium insertion properties of these materials were evaluated by galvanostatic measurements taken using coin-type cells, in view of their application as electrode for rechargeable Li-ion batteries. The mesoporous TiO2 microspheres showed good performances, with a specific reversible capacity of 145 and 128 mAh g−1 at C/2 and C, respectively (C = 335.6 mA g−1), good coulombic efficiency, and a moderate capacity fade (6 %) from the 2nd to the 20th cycle at C/20. Although the addition of V effectively increased the electronic conductivity of the powders, the specific reversible capacity and cycling performances of the TiO2–V2O5 samples were only minimally improved for a 5 at% V loading and were lower at higher V loading. Graphical Abstract: [Figure not available: see fulltext.]
| Original language | English |
|---|---|
| Pages (from-to) | 270-278 |
| Number of pages | 9 |
| Journal | Journal of Sol-Gel Science and Technology |
| Volume | 79 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 1 Aug 2016 |
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Keywords
- Lithium battery
- Mesoporous xerogel
- Non-hydrolytic sol–gel
- Titania
- Vanadia
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Biomaterials
- Condensed Matter Physics
- Materials Chemistry
Fields of Expertise
- Advanced Materials Science
Cite this
Lithium insertion properties of mesoporous nanocrystalline TiO2 and TiO2–V2O5 microspheres prepared by non-hydrolytic sol–gel. / Escamilla-Pérez, A. M.; Louvain, N.; Kaschowitz, M.; Freunberger, S.; Fontaine, O.; Boury, B.; Brun, N.; Mutin, P. H.
In: Journal of Sol-Gel Science and Technology, Vol. 79, No. 2, 01.08.2016, p. 270-278.Research output: Contribution to journal › Article › Research › peer-review
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TY - JOUR
T1 - Lithium insertion properties of mesoporous nanocrystalline TiO2 and TiO2–V2O5 microspheres prepared by non-hydrolytic sol–gel
AU - Escamilla-Pérez, A. M.
AU - Louvain, N.
AU - Kaschowitz, M.
AU - Freunberger, S.
AU - Fontaine, O.
AU - Boury, B.
AU - Brun, N.
AU - Mutin, P. H.
PY - 2016/8/1
Y1 - 2016/8/1
N2 - Abstract: Mesoporous nanocrystalline TiO2 and TiO2–V2O5 microspheres were prepared by non-hydrolytic sol–gel from TiCl4, VOCl3, and iPr2O at 110 °C without any solvent or additives. The samples were characterized by elemental analysis, X-ray diffraction, Raman spectroscopy, scanning electron microscopy, nitrogen physisorption, and impedance measurements. At low vanadium loadings, only TiO2 anatase was detected, and V2O5 scherbinaite was also detected at high vanadium loadings. The texture of the samples depended on the V loading, but all the samples appeared built of primary nanoparticles (≈10–20 nm in size) that aggregate to form mesoporous micron-sized spheres. The lithium insertion properties of these materials were evaluated by galvanostatic measurements taken using coin-type cells, in view of their application as electrode for rechargeable Li-ion batteries. The mesoporous TiO2 microspheres showed good performances, with a specific reversible capacity of 145 and 128 mAh g−1 at C/2 and C, respectively (C = 335.6 mA g−1), good coulombic efficiency, and a moderate capacity fade (6 %) from the 2nd to the 20th cycle at C/20. Although the addition of V effectively increased the electronic conductivity of the powders, the specific reversible capacity and cycling performances of the TiO2–V2O5 samples were only minimally improved for a 5 at% V loading and were lower at higher V loading. Graphical Abstract: [Figure not available: see fulltext.]
AB - Abstract: Mesoporous nanocrystalline TiO2 and TiO2–V2O5 microspheres were prepared by non-hydrolytic sol–gel from TiCl4, VOCl3, and iPr2O at 110 °C without any solvent or additives. The samples were characterized by elemental analysis, X-ray diffraction, Raman spectroscopy, scanning electron microscopy, nitrogen physisorption, and impedance measurements. At low vanadium loadings, only TiO2 anatase was detected, and V2O5 scherbinaite was also detected at high vanadium loadings. The texture of the samples depended on the V loading, but all the samples appeared built of primary nanoparticles (≈10–20 nm in size) that aggregate to form mesoporous micron-sized spheres. The lithium insertion properties of these materials were evaluated by galvanostatic measurements taken using coin-type cells, in view of their application as electrode for rechargeable Li-ion batteries. The mesoporous TiO2 microspheres showed good performances, with a specific reversible capacity of 145 and 128 mAh g−1 at C/2 and C, respectively (C = 335.6 mA g−1), good coulombic efficiency, and a moderate capacity fade (6 %) from the 2nd to the 20th cycle at C/20. Although the addition of V effectively increased the electronic conductivity of the powders, the specific reversible capacity and cycling performances of the TiO2–V2O5 samples were only minimally improved for a 5 at% V loading and were lower at higher V loading. Graphical Abstract: [Figure not available: see fulltext.]
KW - Lithium battery
KW - Mesoporous xerogel
KW - Non-hydrolytic sol–gel
KW - Titania
KW - Vanadia
UR - http://www.scopus.com/inward/record.url?scp=84964049166&partnerID=8YFLogxK
U2 - 10.1007/s10971-016-4037-9
DO - 10.1007/s10971-016-4037-9
M3 - Article
VL - 79
SP - 270
EP - 278
JO - Journal of sol gel science and technology
JF - Journal of sol gel science and technology
SN - 0928-0707
IS - 2
ER -