Hexnuclear cadmium(Ii) cluster constructed from tris(2-methylpyridyl)amine (tpa) and azides

Franz-Andreas Mautner*, Roland Fischer, Bailey R. Williams, Salah S. Massoud, Nahed M.H. Salem

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

A novel rare hexa nuclear cadmium(II)–azide cluster, [Cd 6(TPA) 43-1,1,3-N 3) 42-1,1-N 3) 6](ClO 4) 2·2H 2O (1) was isolated and structurally characterized, in which the azide ligands reveal μ-1,1,3- and μ-1,1-N 3 bridging modes.

Original languageEnglish
Article number317
JournalCrystals
Volume10
Issue number4
DOIs
Publication statusPublished - Apr 2020

Keywords

  • bridged azide
  • cadmium
  • cluster
  • luminescence emission
  • poylnuclear
  • X-ray

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Chemical Engineering(all)
  • Materials Science(all)
  • Inorganic Chemistry

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