Elimination of Bis(trimethylsilyl)stannylene from Tris(trimethylsilyl)stannylated Zirconocene and Hafnocene Chlorides

Roland Fischer; Christoph Marschner

doi:10.1016/j.mencom.2022.01.016

Elimination of Bis(trimethylsilyl)stannylene from Tris(trimethylsilyl)stannylated Zirconocene and Hafnocene Chlorides

Roland Fischer^*, Christoph Marschner^*

^*Corresponding author for this work

Institute of Inorganic Chemistry (6330)

Research output: Contribution to journal › Article › peer-review

Abstract

Reactions of (Me ₃Si) ₃SnK with Cp ₂MCl ₂ (M = Zr, Hf) give the respective stannylated metallocene chlorides. These complexes display a tendency to eliminate bis(trimethylsilyl)-stannylene under Cp ₂M(Cl)SiMe ₃ formation.

Original language	English
Pages (from-to)	52-53
Number of pages	2
Journal	Mendeleev Communications
Volume	32
Issue number	1
DOIs	https://doi.org/10.1016/j.mencom.2022.01.016
Publication status	Published - 1 Jan 2022

Keywords

Group 4 elements
Hafnium
Metallocenes
Silicon
Stannylated compounds
Stannylene
Tin
Zirconium

ASJC Scopus subject areas

Chemistry(all)

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10.1016/j.mencom.2022.01.016

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title = "Elimination of Bis(trimethylsilyl)stannylene from Tris(trimethylsilyl)stannylated Zirconocene and Hafnocene Chlorides",

abstract = "Reactions of (Me 3Si) 3SnK with Cp 2MCl 2 (M = Zr, Hf) give the respective stannylated metallocene chlorides. These complexes display a tendency to eliminate bis(trimethylsilyl)-stannylene under Cp 2M(Cl)SiMe 3 formation. ",

keywords = "Group 4 elements, Hafnium, Metallocenes, Silicon, Stannylated compounds, Stannylene, Tin, Zirconium",

author = "Roland Fischer and Christoph Marschner",

year = "2022",

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doi = "10.1016/j.mencom.2022.01.016",

language = "English",

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journal = "Mendeleev Communications",

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AU - Fischer, Roland

AU - Marschner, Christoph

PY - 2022/1/1

Y1 - 2022/1/1

N2 - Reactions of (Me 3Si) 3SnK with Cp 2MCl 2 (M = Zr, Hf) give the respective stannylated metallocene chlorides. These complexes display a tendency to eliminate bis(trimethylsilyl)-stannylene under Cp 2M(Cl)SiMe 3 formation.

AB - Reactions of (Me 3Si) 3SnK with Cp 2MCl 2 (M = Zr, Hf) give the respective stannylated metallocene chlorides. These complexes display a tendency to eliminate bis(trimethylsilyl)-stannylene under Cp 2M(Cl)SiMe 3 formation.

KW - Group 4 elements

KW - Hafnium

KW - Metallocenes

KW - Silicon

KW - Stannylated compounds

KW - Stannylene

KW - Tin

KW - Zirconium

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U2 - 10.1016/j.mencom.2022.01.016

DO - 10.1016/j.mencom.2022.01.016

M3 - Article

SN - 0959-9436

VL - 32

SP - 52

EP - 53

JO - Mendeleev Communications

JF - Mendeleev Communications

IS - 1

ER -

Elimination of Bis(trimethylsilyl)stannylene from Tris(trimethylsilyl)stannylated Zirconocene and Hafnocene Chlorides

Abstract

Keywords

ASJC Scopus subject areas

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