Electrogeneration of peroxodicarbonate anion: Syntheses of tetraalkylammonium silylcarboxylate

K. N. Singh; Susanna Neuhold; Christa Grogger; V. V. Jouikov

doi:10.1134/S1023193507100102

Electrogeneration of peroxodicarbonate anion: Syntheses of tetraalkylammonium silylcarboxylate

K. N. Singh, Susanna Neuhold, Christa Grogger, V. V. Jouikov

Institute of Inorganic Chemistry (6330)

Research output: Contribution to journal › Article › peer-review

Abstract

Oxygen electroreduction in the presence of CO2 in acetonitrile solutions of tetraalkylammonium salts is a means to produce tetraalkylammonium peroxodicarboxylates. The latter react with triorganosilanes R3SiH to yield tetraalkylammonium salts of triorganylsilylcarboxylic acids. Diorganylsilanes under the same conditions produce cyclic siloxanes exclusively.

Original language	English
Pages (from-to)	1170-1174
Journal	Russian Journal of Electrochemistry
Volume	43
Issue number	10
DOIs	https://doi.org/10.1134/S1023193507100102
Publication status	Published - 2007

Treatment code (Nähere Zuordnung)

Basic - Fundamental (Grundlagenforschung)
Experimental

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10.1134/S1023193507100102

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title = "Electrogeneration of peroxodicarbonate anion: Syntheses of tetraalkylammonium silylcarboxylate",

abstract = "Oxygen electroreduction in the presence of CO2 in acetonitrile solutions of tetraalkylammonium salts is a means to produce tetraalkylammonium peroxodicarboxylates. The latter react with triorganosilanes R3SiH to yield tetraalkylammonium salts of triorganylsilylcarboxylic acids. Diorganylsilanes under the same conditions produce cyclic siloxanes exclusively.",

author = "Singh, {K. N.} and Susanna Neuhold and Christa Grogger and Jouikov, {V. V.}",

year = "2007",

doi = "10.1134/S1023193507100102",

language = "English",

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pages = "1170--1174",

journal = "Russian Journal of Electrochemistry ",

issn = "1608-3342 ",

publisher = "Springer Science+Business Media B.V ",

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T1 - Electrogeneration of peroxodicarbonate anion: Syntheses of tetraalkylammonium silylcarboxylate

AU - Singh, K. N.

AU - Neuhold, Susanna

AU - Grogger, Christa

AU - Jouikov, V. V.

PY - 2007

Y1 - 2007

N2 - Oxygen electroreduction in the presence of CO2 in acetonitrile solutions of tetraalkylammonium salts is a means to produce tetraalkylammonium peroxodicarboxylates. The latter react with triorganosilanes R3SiH to yield tetraalkylammonium salts of triorganylsilylcarboxylic acids. Diorganylsilanes under the same conditions produce cyclic siloxanes exclusively.

AB - Oxygen electroreduction in the presence of CO2 in acetonitrile solutions of tetraalkylammonium salts is a means to produce tetraalkylammonium peroxodicarboxylates. The latter react with triorganosilanes R3SiH to yield tetraalkylammonium salts of triorganylsilylcarboxylic acids. Diorganylsilanes under the same conditions produce cyclic siloxanes exclusively.

U2 - 10.1134/S1023193507100102

DO - 10.1134/S1023193507100102

M3 - Article

SN - 1608-3342

VL - 43

SP - 1170

EP - 1174

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

IS - 10

ER -

Electrogeneration of peroxodicarbonate anion: Syntheses of tetraalkylammonium silylcarboxylate

Abstract

Treatment code (Nähere Zuordnung)

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