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Solid alkali metal carbonates are universal passivation layer components of intercalation battery materials and common side products in metal-O2 batteries, and are believed to form and decompose reversibly in metal-O2/CO2 cells. In these cathodes, Li2CO3 decomposes to CO2 when exposed to potentials above 3.8 V vs. Li/Li+. However, O2 evolution, as would be expected according to the decomposition reaction 2 Li2CO3→4 Li++4 e−+2 CO2+O2, is not detected. O atoms are thus unaccounted for, which was previously ascribed to unidentified parasitic reactions. Here, we show that highly reactive singlet oxygen (1O2) forms upon oxidizing Li2CO3 in an aprotic electrolyte and therefore does not evolve as O2. These results have substantial implications for the long-term cyclability of batteries: they underpin the importance of avoiding 1O2 in metal-O2 batteries, question the possibility of a reversible metal-O2/CO2 battery based on a carbonate discharge product, and help explain the interfacial reactivity of transition-metal cathodes with residual Li2CO3.
Fields of Expertise
- Advanced Materials Science
FingerprintDive into the research topics of 'Electrochemical Oxidation of Lithium Carbonate Generates Singlet Oxygen'. Together they form a unique fingerprint.
- 1 Finished
Stefan Freunberger (Speaker)5 Aug 2019
Activity: Talk or presentation › Invited talk › Science to science
Freunberger, Stefan (Recipient), 18 May 2017
Prize: Prizes / Medals / Awards