Discriminating the Mobile Ions from the Immobile Ones in Li4+xTi5O12: 6Li NMR Reveals the Main Li+ Diffusion Pathway and Proposes a Refined Lithiation Mechanism

Walter Schmidt, Martin Wilkening

Research output: Contribution to journalArticleResearchpeer-review

Abstract

One of the most widely known anode materials with excellent cycling performance in lithium-ion batteries is zero-strain lithium titanate Li4Ti5O12 (LTO). This is based on the highly reversible insertion and deinsertion of Li ions varying the composition of Li4+xTi5O12 from x = 0 to x = 3. The facile incorporation of Li is tightly connected with bulk Li ion dynamics. Although macroscopic electrochemical properties have been studied in great detail, bulk Li ion diffusion pathways have rarely been probed experimentally from an atomic scale point of view. Here, we evaluated 1D and 2D 6Li magic angle spinning (MAS) NMR spectra recorded as a function of x to make the local magnetic changes during Li insertion visible. This enabled us to directly show that rapid Li exchange involves the 8a and 16c sites, forming a 3D network throughout the LTO spinel structure. In contrast, considering the time scale set by our NMR experiments, the Li ions residing on the mixed occupied octahedral positions 16d are quite immobile. Under the MAS conditions applied, they definitely do not participate in rapid Li self-diffusion as evidenced by rather long site-specific longitudinal relaxation times as well as the absence of any NMR coalescence effects. Based on the NMR spectra, we propose a refined Li insertion mechanism which includes the initial formation of a highly conducting quasi solid solution characterized by rapid Li ion exchange.

Original languageEnglish
Pages (from-to)11372-11381
Number of pages10
JournalJournal of Physical Chemistry C
Volume120
Issue number21
DOIs
Publication statusPublished - 2 Jun 2016

Fingerprint

Nuclear magnetic resonance
Ions
nuclear magnetic resonance
Magic angle spinning
insertion
ions
metal spinning
lithium
Coalescence
Electrochemical properties
Lithium
Relaxation time
Solid solutions
Ion exchange
Anodes
coalescing
spinel
electric batteries
anodes
solid solutions

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

Discriminating the Mobile Ions from the Immobile Ones in Li4+xTi5O12 : 6Li NMR Reveals the Main Li+ Diffusion Pathway and Proposes a Refined Lithiation Mechanism. / Schmidt, Walter; Wilkening, Martin.

In: Journal of Physical Chemistry C, Vol. 120, No. 21, 02.06.2016, p. 11372-11381.

Research output: Contribution to journalArticleResearchpeer-review

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