Designing biochar properties through the blending of biomass feedstock with metals: Impact on oxyanions adsorption behavior

Alba Dieguez-Alonso, Andrés Anca-Couce, Vladimír Frišták, Eduardo Moreno-Jiménez, Markus Bacher, Thomas D. Bucheli, Giulia Cimò, Pellegrino Conte, Nikolas Hagemann, Andreas Haller, Isabel Hilber, Olivier Husson, Claudia I. Kammann, Norbert Kienzl, Jens Leifeld, Thomas Rosenau, Gerhard Soja, Hans Peter Schmidt

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Metal-blending of biomass prior to pyrolysis is investigated in this work as a tool to modify biochar physico-chemical properties and its behavior as adsorbent. Six different compounds were used for metal-blending: AlCl3, Cu(OH)2, FeSO4, KCl, MgCl2 and Mg(OH)2. Pyrolysis experiments were performed at 400 and 700 °C and the characterization of biochar properties included: elemental composition, thermal stability, surface area and pore size distribution, Zeta potential, redox potential, chemical structure (with nuclear magnetic resonance) and adsorption behavior of arsenate, phosphate and nitrate. Metalblending strongly affected biochars’ surface charge and redox potential. Moreover, it increased biochars’ microporosity (per mass of organic carbon). For most biochars, mesoporosity was also increased. The adsorption behavior was enhanced for all metal-blended biochars, although with significant differences across species: Mg(OH)2-blended biochar produced at 400 °C showed the highest phosphate adsorption capacity (Langmuir Qmax approx. 250 mg g−1), while AlCl3-blended biochar produced also at 400 °C showed the highest arsenate adsorption (Langmuir Qmax approx. 14 mg g−1). Significant differences were present, even for the same biochar, with respect to the investigated oxyanions. This indicates that biochar properties need to be optimized for each application, but also that this optimization can be achieved with tools such as metal-blending. These results constitute a significant contribution towards the production of designer biochars.

LanguageEnglish
Pages743-753
Number of pages11
JournalChemosphere
Volume214
DOIs
StatusPublished - 1 Jan 2019

Fingerprint

Biomass
Feedstocks
Adsorption
Metals
adsorption
metal
biomass
arsenate
redox potential
pyrolysis
Phosphates
Pyrolysis
phosphate
Microporosity
Zeta potential
Surface charge
Organic carbon
Adsorbents
Chemical properties
Pore size

Keywords

  • Adsorption
  • Designer biochar
  • Metal-blending
  • Oxyanion
  • Physico-chemical
  • Pore size distribution

ASJC Scopus subject areas

  • Environmental Engineering
  • Environmental Chemistry
  • Chemistry(all)
  • Pollution
  • Health, Toxicology and Mutagenesis

Cite this

Designing biochar properties through the blending of biomass feedstock with metals : Impact on oxyanions adsorption behavior. / Dieguez-Alonso, Alba; Anca-Couce, Andrés; Frišták, Vladimír; Moreno-Jiménez, Eduardo; Bacher, Markus; Bucheli, Thomas D.; Cimò, Giulia; Conte, Pellegrino; Hagemann, Nikolas; Haller, Andreas; Hilber, Isabel; Husson, Olivier; Kammann, Claudia I.; Kienzl, Norbert; Leifeld, Jens; Rosenau, Thomas; Soja, Gerhard; Schmidt, Hans Peter.

In: Chemosphere, Vol. 214, 01.01.2019, p. 743-753.

Research output: Contribution to journalArticleResearchpeer-review

Dieguez-Alonso, A, Anca-Couce, A, Frišták, V, Moreno-Jiménez, E, Bacher, M, Bucheli, TD, Cimò, G, Conte, P, Hagemann, N, Haller, A, Hilber, I, Husson, O, Kammann, CI, Kienzl, N, Leifeld, J, Rosenau, T, Soja, G & Schmidt, HP 2019, 'Designing biochar properties through the blending of biomass feedstock with metals: Impact on oxyanions adsorption behavior', Chemosphere, vol. 214, pp. 743-753. https://doi.org/10.1016/j.chemosphere.2018.09.091
Dieguez-Alonso, Alba ; Anca-Couce, Andrés ; Frišták, Vladimír ; Moreno-Jiménez, Eduardo ; Bacher, Markus ; Bucheli, Thomas D. ; Cimò, Giulia ; Conte, Pellegrino ; Hagemann, Nikolas ; Haller, Andreas ; Hilber, Isabel ; Husson, Olivier ; Kammann, Claudia I. ; Kienzl, Norbert ; Leifeld, Jens ; Rosenau, Thomas ; Soja, Gerhard ; Schmidt, Hans Peter. / Designing biochar properties through the blending of biomass feedstock with metals : Impact on oxyanions adsorption behavior. In: Chemosphere. 2019 ; Vol. 214. pp. 743-753.
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abstract = "Metal-blending of biomass prior to pyrolysis is investigated in this work as a tool to modify biochar physico-chemical properties and its behavior as adsorbent. Six different compounds were used for metal-blending: AlCl3, Cu(OH)2, FeSO4, KCl, MgCl2 and Mg(OH)2. Pyrolysis experiments were performed at 400 and 700 °C and the characterization of biochar properties included: elemental composition, thermal stability, surface area and pore size distribution, Zeta potential, redox potential, chemical structure (with nuclear magnetic resonance) and adsorption behavior of arsenate, phosphate and nitrate. Metalblending strongly affected biochars’ surface charge and redox potential. Moreover, it increased biochars’ microporosity (per mass of organic carbon). For most biochars, mesoporosity was also increased. The adsorption behavior was enhanced for all metal-blended biochars, although with significant differences across species: Mg(OH)2-blended biochar produced at 400 °C showed the highest phosphate adsorption capacity (Langmuir Qmax approx. 250 mg g−1), while AlCl3-blended biochar produced also at 400 °C showed the highest arsenate adsorption (Langmuir Qmax approx. 14 mg g−1). Significant differences were present, even for the same biochar, with respect to the investigated oxyanions. This indicates that biochar properties need to be optimized for each application, but also that this optimization can be achieved with tools such as metal-blending. These results constitute a significant contribution towards the production of designer biochars.",
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AU - Dieguez-Alonso, Alba

AU - Anca-Couce, Andrés

AU - Frišták, Vladimír

AU - Moreno-Jiménez, Eduardo

AU - Bacher, Markus

AU - Bucheli, Thomas D.

AU - Cimò, Giulia

AU - Conte, Pellegrino

AU - Hagemann, Nikolas

AU - Haller, Andreas

AU - Hilber, Isabel

AU - Husson, Olivier

AU - Kammann, Claudia I.

AU - Kienzl, Norbert

AU - Leifeld, Jens

AU - Rosenau, Thomas

AU - Soja, Gerhard

AU - Schmidt, Hans Peter

N1 - Copyright © 2018 Elsevier Ltd. All rights reserved.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Metal-blending of biomass prior to pyrolysis is investigated in this work as a tool to modify biochar physico-chemical properties and its behavior as adsorbent. Six different compounds were used for metal-blending: AlCl3, Cu(OH)2, FeSO4, KCl, MgCl2 and Mg(OH)2. Pyrolysis experiments were performed at 400 and 700 °C and the characterization of biochar properties included: elemental composition, thermal stability, surface area and pore size distribution, Zeta potential, redox potential, chemical structure (with nuclear magnetic resonance) and adsorption behavior of arsenate, phosphate and nitrate. Metalblending strongly affected biochars’ surface charge and redox potential. Moreover, it increased biochars’ microporosity (per mass of organic carbon). For most biochars, mesoporosity was also increased. The adsorption behavior was enhanced for all metal-blended biochars, although with significant differences across species: Mg(OH)2-blended biochar produced at 400 °C showed the highest phosphate adsorption capacity (Langmuir Qmax approx. 250 mg g−1), while AlCl3-blended biochar produced also at 400 °C showed the highest arsenate adsorption (Langmuir Qmax approx. 14 mg g−1). Significant differences were present, even for the same biochar, with respect to the investigated oxyanions. This indicates that biochar properties need to be optimized for each application, but also that this optimization can be achieved with tools such as metal-blending. These results constitute a significant contribution towards the production of designer biochars.

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