Copper(II) Complexes Derived from 3-Phosphonopropionic acid: Crystal Structures and Magnetic Behaviour

Franz A. Mautner; Salah M. El Fallah; Saskia Speed; Ramon Vicente

doi:10.1016/j.poly.2014.05.046

Copper(II) Complexes Derived from 3-Phosphonopropionic acid: Crystal Structures and Magnetic Behaviour

Franz A. Mautner, Salah M. El Fallah, Saskia Speed^*, Ramon Vicente^*

^*Corresponding author for this work

Institute of Physical and Theoretical Chemistry (6350)

Research output: Contribution to journal › Article › peer-review

Abstract

The syntheses, structural characterization and magnetic behaviour of three new copper(II) complexes derived from 3-phosphonopropionic acid with formulae [Cu2(HO3PCH2CH2CO2)2(bpy)2(H2O)2] (1), [Cu(HO3PCH2CH2CO2)(Me2phen)]n (2) and [Cu{(py)2C(OH)2}](HO3PCH2CH2CO2H)2 (3) are reported (H2O3PCH2CH2CO2H = 3-phosphonopropionic acid, bpy = 2,2′-bipyridyl, Me2phen = 2,9-dimethyl-1,10-phenanthroline, (py)2C(OH)2 = bis(2-pyridyl)methanediol). 1 is a dinuclear compound with hydrogen-3-phosphonopropionate(2-) bridging ligands, 2 is a ladder type monodimensional compound with the same HO3PCH2CH2CO2(2-) bridging ligand and 3 is a mononuclear compound with isolated HO3PCH2CH2CO2H(1-) anions. The magnetic properties of the 1D compound are reported.

Original language	English
Pages (from-to)	1-5
Journal	Polyhedron
Volume	81
DOIs	https://doi.org/10.1016/j.poly.2014.05.046
Publication status	Published - 2014

Fields of Expertise

Advanced Materials Science

Treatment code (Nähere Zuordnung)

Basic - Fundamental (Grundlagenforschung)

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10.1016/j.poly.2014.05.046

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@article{689e1071ab714661bc847676241c774c,

title = "Copper(II) Complexes Derived from 3-Phosphonopropionic acid: Crystal Structures and Magnetic Behaviour",

abstract = "The syntheses, structural characterization and magnetic behaviour of three new copper(II) complexes derived from 3-phosphonopropionic acid with formulae [Cu2(HO3PCH2CH2CO2)2(bpy)2(H2O)2] (1), [Cu(HO3PCH2CH2CO2)(Me2phen)]n (2) and [Cu{(py)2C(OH)2}](HO3PCH2CH2CO2H)2 (3) are reported (H2O3PCH2CH2CO2H = 3-phosphonopropionic acid, bpy = 2,2′-bipyridyl, Me2phen = 2,9-dimethyl-1,10-phenanthroline, (py)2C(OH)2 = bis(2-pyridyl)methanediol). 1 is a dinuclear compound with hydrogen-3-phosphonopropionate(2-) bridging ligands, 2 is a ladder type monodimensional compound with the same HO3PCH2CH2CO2(2-) bridging ligand and 3 is a mononuclear compound with isolated HO3PCH2CH2CO2H(1-) anions. The magnetic properties of the 1D compound are reported.",

author = "Mautner, {Franz A.} and {El Fallah}, {Salah M.} and Saskia Speed and Ramon Vicente",

year = "2014",

doi = "10.1016/j.poly.2014.05.046",

language = "English",

volume = "81",

pages = "1--5",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

}

TY - JOUR

T1 - Copper(II) Complexes Derived from 3-Phosphonopropionic acid: Crystal Structures and Magnetic Behaviour

AU - Mautner, Franz A.

AU - El Fallah, Salah M.

AU - Speed, Saskia

AU - Vicente, Ramon

PY - 2014

Y1 - 2014

N2 - The syntheses, structural characterization and magnetic behaviour of three new copper(II) complexes derived from 3-phosphonopropionic acid with formulae [Cu2(HO3PCH2CH2CO2)2(bpy)2(H2O)2] (1), [Cu(HO3PCH2CH2CO2)(Me2phen)]n (2) and [Cu{(py)2C(OH)2}](HO3PCH2CH2CO2H)2 (3) are reported (H2O3PCH2CH2CO2H = 3-phosphonopropionic acid, bpy = 2,2′-bipyridyl, Me2phen = 2,9-dimethyl-1,10-phenanthroline, (py)2C(OH)2 = bis(2-pyridyl)methanediol). 1 is a dinuclear compound with hydrogen-3-phosphonopropionate(2-) bridging ligands, 2 is a ladder type monodimensional compound with the same HO3PCH2CH2CO2(2-) bridging ligand and 3 is a mononuclear compound with isolated HO3PCH2CH2CO2H(1-) anions. The magnetic properties of the 1D compound are reported.

AB - The syntheses, structural characterization and magnetic behaviour of three new copper(II) complexes derived from 3-phosphonopropionic acid with formulae [Cu2(HO3PCH2CH2CO2)2(bpy)2(H2O)2] (1), [Cu(HO3PCH2CH2CO2)(Me2phen)]n (2) and [Cu{(py)2C(OH)2}](HO3PCH2CH2CO2H)2 (3) are reported (H2O3PCH2CH2CO2H = 3-phosphonopropionic acid, bpy = 2,2′-bipyridyl, Me2phen = 2,9-dimethyl-1,10-phenanthroline, (py)2C(OH)2 = bis(2-pyridyl)methanediol). 1 is a dinuclear compound with hydrogen-3-phosphonopropionate(2-) bridging ligands, 2 is a ladder type monodimensional compound with the same HO3PCH2CH2CO2(2-) bridging ligand and 3 is a mononuclear compound with isolated HO3PCH2CH2CO2H(1-) anions. The magnetic properties of the 1D compound are reported.

U2 - 10.1016/j.poly.2014.05.046

DO - 10.1016/j.poly.2014.05.046

M3 - Article

SN - 0277-5387

VL - 81

SP - 1

EP - 5

JO - Polyhedron

JF - Polyhedron

ER -

Copper(II) Complexes Derived from 3-Phosphonopropionic acid: Crystal Structures and Magnetic Behaviour

Abstract

Fields of Expertise

Treatment code (Nähere Zuordnung)

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