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Abstract
Oxidation of the primary alcohol group in the kanamycin A derivative 2 b with simultaneous P-elimination gave the a$-unsaturated aldehyde 3 a of which the derivatives 3 b - e were prepared by acetalisation, oxidation, or reduction. Hydrogenation of the double bond led to 4"-deoxy-5"- epi-kanarnycin A derivatives.
Translated title of the contribution | Chemical Modification of Kanamycin A. - Derivatives Containing a 4,J-Double Bond in the Kanosamine Part |
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Original language | German |
Pages (from-to) | 644-649 |
Journal | Liebigs Annalen der Chemie (1979 - 1994) |
Volume | 1985 |
Issue number | 3 |
Publication status | Published - 1985 |
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