TY - JOUR
T1 - Towards a recuperative, stationary operated thermochemical reformer
T2 - Experimental investigations on the methane conversion and waste heat recovery
AU - Wachter, Philipp
AU - Gaber, Christian
AU - Demuth, Martin
AU - Hochenauer, Christoph
PY - 2021/1/25
Y1 - 2021/1/25
N2 - In this article, stationary operated, thermochemical recuperation (TCR) based on internal reforming of methane, using oxy-fuel exhaust gases as both heat source and as reactants, is considered. TCR is a promising technology for effective heat recovery from exhaust gases of oxy-fuel furnaces, which could deliver significant increases in combustion efficiency. In order to quantify and validate the potential of TCR, the influence of the main operational parameters on methane conversion and waste heat recovery was experimentally investigated. The experimental investigations presented here differ from previously published work in the following aspects: (I) A stationary, recuperative lab-scale reformer unit filled with industrial nickel catalyst was used to investigate the influence of the oxy-fuel exhaust gas temperature, the exhaust gas recirculation rate and the addition of oxygen to the reactants on the methane conversion and waste heat recovery. (II) The required energy input for the endothermic reforming reaction is provided solely by the thermal energy of the oxy-fuel exhaust gases. (III) The reactants for fuel reforming were exclusively taken from oxy-fuel exhaust gases, resulting in so-called bi- and tri-reforming of methane, depending on the addition of oxygen. The results showed that a maximum CH4 conversion rate of 65.6% was achieved, with a substantial increase in the combustion efficiency of 17.9%, confirming the ability of TCR to improve the combustion efficiency of oxy-fuel furnaces. In addition, the effects of different reactor configurations on the methane conversion were investigated.
AB - In this article, stationary operated, thermochemical recuperation (TCR) based on internal reforming of methane, using oxy-fuel exhaust gases as both heat source and as reactants, is considered. TCR is a promising technology for effective heat recovery from exhaust gases of oxy-fuel furnaces, which could deliver significant increases in combustion efficiency. In order to quantify and validate the potential of TCR, the influence of the main operational parameters on methane conversion and waste heat recovery was experimentally investigated. The experimental investigations presented here differ from previously published work in the following aspects: (I) A stationary, recuperative lab-scale reformer unit filled with industrial nickel catalyst was used to investigate the influence of the oxy-fuel exhaust gas temperature, the exhaust gas recirculation rate and the addition of oxygen to the reactants on the methane conversion and waste heat recovery. (II) The required energy input for the endothermic reforming reaction is provided solely by the thermal energy of the oxy-fuel exhaust gases. (III) The reactants for fuel reforming were exclusively taken from oxy-fuel exhaust gases, resulting in so-called bi- and tri-reforming of methane, depending on the addition of oxygen. The results showed that a maximum CH4 conversion rate of 65.6% was achieved, with a substantial increase in the combustion efficiency of 17.9%, confirming the ability of TCR to improve the combustion efficiency of oxy-fuel furnaces. In addition, the effects of different reactor configurations on the methane conversion were investigated.
KW - Bi- and tri-reforming
KW - Ni catalyst
KW - Oxy-fuel combustion
KW - Thermochemical recuperation
KW - Waste heat recovery
UR - http://www.scopus.com/inward/record.url?scp=85093659179&partnerID=8YFLogxK
U2 - 10.1016/j.applthermaleng.2020.116121
DO - 10.1016/j.applthermaleng.2020.116121
M3 - Article
AN - SCOPUS:85093659179
SN - 1359-4311
VL - 183
JO - Applied Thermal Engineering
JF - Applied Thermal Engineering
M1 - 116121
ER -