The LiHg(22Π3/2-X2Σ1/2 +) system

Dieter Karlheinz Gruber; X. Li; Laurentius Windholz; M. M. Gleichmann; B. A. Hess; I. Vezmar; G. Pichler

The LiHg(2²Π_3/2-X²Σ_1/2 ⁺) system

Dieter Karlheinz Gruber, X. Li, Laurentius Windholz, M. M. Gleichmann, B. A. Hess, I. Vezmar, G. Pichler

Institut für Experimentalphysik (5110)

Publikation: Beitrag in einer Fachzeitschrift › Artikel › Begutachtung

Abstract

We report the determination of the complete LiHg shallow bound ground state potential curve by combination of laser-induced fluorescence spectroscopy of bound-bound transitions, photoassociation spectroscopy of bound-free transitions, and ab initio calculations. The results are evaluated by comparison of quantum mechanically simulated emission spectra with experimental data and used to describe spectroscopic features of the 2²Π_3/2-X²Σ_1/2⁺ band as well as the photochemical formation via excitation of the lithium dimer.

Originalsprache	englisch
Seiten (von - bis)	10062-10069
Seitenumfang	8
Fachzeitschrift	The Journal of Physical Chemistry
Jahrgang	100
Ausgabenummer	24
Publikationsstatus	Veröffentlicht - 13 Juni 1996

ASJC Scopus subject areas

Physikalische und Theoretische Chemie

Fields of Expertise

Sonstiges

Andere Dateien und Links

http://www.scopus.com/inward/record.url?scp=0344890683&partnerID=8YFLogxK

Dieses zitieren

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abstract = "We report the determination of the complete LiHg shallow bound ground state potential curve by combination of laser-induced fluorescence spectroscopy of bound-bound transitions, photoassociation spectroscopy of bound-free transitions, and ab initio calculations. The results are evaluated by comparison of quantum mechanically simulated emission spectra with experimental data and used to describe spectroscopic features of the 22Π3/2-X2Σ1/2+ band as well as the photochemical formation via excitation of the lithium dimer.",

author = "Gruber, {Dieter Karlheinz} and X. Li and Laurentius Windholz and Gleichmann, {M. M.} and Hess, {B. A.} and I. Vezmar and G. Pichler",

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AU - Gruber, Dieter Karlheinz

AU - Li, X.

AU - Windholz, Laurentius

AU - Gleichmann, M. M.

AU - Hess, B. A.

AU - Vezmar, I.

AU - Pichler, G.

PY - 1996/6/13

Y1 - 1996/6/13

N2 - We report the determination of the complete LiHg shallow bound ground state potential curve by combination of laser-induced fluorescence spectroscopy of bound-bound transitions, photoassociation spectroscopy of bound-free transitions, and ab initio calculations. The results are evaluated by comparison of quantum mechanically simulated emission spectra with experimental data and used to describe spectroscopic features of the 22Π3/2-X2Σ1/2+ band as well as the photochemical formation via excitation of the lithium dimer.

AB - We report the determination of the complete LiHg shallow bound ground state potential curve by combination of laser-induced fluorescence spectroscopy of bound-bound transitions, photoassociation spectroscopy of bound-free transitions, and ab initio calculations. The results are evaluated by comparison of quantum mechanically simulated emission spectra with experimental data and used to describe spectroscopic features of the 22Π3/2-X2Σ1/2+ band as well as the photochemical formation via excitation of the lithium dimer.

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M3 - Article

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JF - The Journal of Physical Chemistry

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