TY - JOUR
T1 - The Electronic Conductivity of Single Crystalline Ga-Stabilized Cubic Li7La3Zr2O12
T2 - A Technologically Relevant Parameter for All-Solid-State Batteries
AU - Philipp, Martin
AU - Gadermaier, Bernhard
AU - Posch, Patrick
AU - Hanzu, Ilie
AU - Ganschow, Steffen
AU - Meven, Martin
AU - Rettenwander, Daniel
AU - Redhammer, Günther J.
AU - Wilkening, H. Martin R.
PY - 2020/8/1
Y1 - 2020/8/1
N2 - The next-generation of all-solid-state lithium batteries need ceramic electrolytes with very high ionic conductivities. At the same time a negligible electronic conductivity σeon is required to eliminate self-discharge in such systems. A non-negligible electronic conductivity may also promote the unintentional formation of Li dendrites, being currently one of the key issues hindering the development of long-lasting all-solid-state batteries. This interplay is suggested recently for garnet-type Li7La3Zr2O12 (LLZO). It is, however, well known that the overall macroscopic electronic conductivity may be governed by a range of extrinsic factors such as impurities, chemical inhomogeneities, grain boundaries, morphology, and size effects. Here, advantage of Czochralski-grown single crystals, which offer the unique opportunity to evaluate intrinsic properties of a chemically homogeneous matrix, is taken to measure the electronic conductivity σeon. Via long-time, high-precision potentiostatic polarization experiments an upper limit of σeon in the order of 5 × 10−10 S cm−1 (293 K) is estimated. This value is by six orders of magnitude lower than the corresponding total conductivity σtotal = 10−3 S cm−1 of Ga-LLZO. Thus, it is concluded that the high values of σeon recently reported for similar systems do not necessarily mirror intragrain bulk properties of chemically homogenous systems but may originate from chemically inhomogeneous interfacial areas.
AB - The next-generation of all-solid-state lithium batteries need ceramic electrolytes with very high ionic conductivities. At the same time a negligible electronic conductivity σeon is required to eliminate self-discharge in such systems. A non-negligible electronic conductivity may also promote the unintentional formation of Li dendrites, being currently one of the key issues hindering the development of long-lasting all-solid-state batteries. This interplay is suggested recently for garnet-type Li7La3Zr2O12 (LLZO). It is, however, well known that the overall macroscopic electronic conductivity may be governed by a range of extrinsic factors such as impurities, chemical inhomogeneities, grain boundaries, morphology, and size effects. Here, advantage of Czochralski-grown single crystals, which offer the unique opportunity to evaluate intrinsic properties of a chemically homogeneous matrix, is taken to measure the electronic conductivity σeon. Via long-time, high-precision potentiostatic polarization experiments an upper limit of σeon in the order of 5 × 10−10 S cm−1 (293 K) is estimated. This value is by six orders of magnitude lower than the corresponding total conductivity σtotal = 10−3 S cm−1 of Ga-LLZO. Thus, it is concluded that the high values of σeon recently reported for similar systems do not necessarily mirror intragrain bulk properties of chemically homogenous systems but may originate from chemically inhomogeneous interfacial areas.
KW - direct current-polarization
KW - electronic conductivity
KW - ionic conductivity
KW - LLZO
KW - single crystals
UR - http://www.scopus.com/inward/record.url?scp=85086268064&partnerID=8YFLogxK
U2 - 10.1002/admi.202000450
DO - 10.1002/admi.202000450
M3 - Article
AN - SCOPUS:85086268064
SN - 2196-7350
VL - 7
JO - Advanced Materials Interfaces
JF - Advanced Materials Interfaces
IS - 16
M1 - 2000450
ER -