Synthesis, Structural Characterization, and Spectroscopy of the Cadmium-Cadmium Bonded Molecular Species Ar'CdCdAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2).

Zhongliang Zhu; Roland C. Fischer; James C. Fettinger; Eric Rivard; Marcin Brynda; Philip P. Power

doi:10.1021/ja066108h

Synthesis, Structural Characterization, and Spectroscopy of the Cadmium-Cadmium Bonded Molecular Species Ar'CdCdAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2).

Zhongliang Zhu, Roland C. Fischer, James C. Fettinger, Eric Rivard, Marcin Brynda, Philip P. Power

Institut für Anorganische Chemie (6330)

Publikation: Beitrag in einer Fachzeitschrift › Artikel › Begutachtung

Abstract

The synthesis and 1st structural characterization of a Cd-Cd bonded mol. compd., Ar'CdCdAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2), are reported. Thus, treating Ar'Li with CdI2 in Et2O for 2 days gave 67.2% Ar'CdI, which upon treatment with NaH in THF for 3 days gave 27.6% Ar'CdCdAr'. The existence of the Cd-Cd bond was established by 113Cd NMR spectroscopy and x-ray diffraction (Cd-Cd = 2.6257(5) Å). Like its Group 12 analog Ar'ZnZnAr', DFT calcns. on a model compd. showed that Ar'CdCdAr' had significant p-character in the Cd-Cd σ-bonding HOMO. [on SciFinder(R)]

Originalsprache	englisch
Seiten (von - bis)	15068-15069
Seitenumfang	2
Fachzeitschrift	Journal of the American Chemical Society
Jahrgang	128
Ausgabenummer	47
DOIs	https://doi.org/10.1021/ja066108h
Publikationsstatus	Veröffentlicht - 2006

Schlagwörter

cadmium cadmium bond bulky terphenyl ligand
dinuclear cadmium terphenyl DFT optimized mol structure HOMO
crystal structure dinuclear cadmium bulky terphenyl ligand prepn
mol structure dinuclear cadmium bulky terphenyl ligand

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10.1021/ja066108h

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Synthesis, Structural Characterization, and Spectroscopy of the Cadmium-Cadmium Bonded Molecular Species Ar'CdCdAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2). / Zhu, Zhongliang; Fischer, Roland C.; Fettinger, James C. et al.
in: Journal of the American Chemical Society, Jahrgang 128, Nr. 47, 2006, S. 15068-15069.

Publikation: Beitrag in einer Fachzeitschrift › Artikel › Begutachtung

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title = "Synthesis, Structural Characterization, and Spectroscopy of the Cadmium-Cadmium Bonded Molecular Species Ar'CdCdAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2).",

abstract = "The synthesis and 1st structural characterization of a Cd-Cd bonded mol. compd., Ar'CdCdAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2), are reported. Thus, treating Ar'Li with CdI2 in Et2O for 2 days gave 67.2% Ar'CdI, which upon treatment with NaH in THF for 3 days gave 27.6% Ar'CdCdAr'. The existence of the Cd-Cd bond was established by 113Cd NMR spectroscopy and x-ray diffraction (Cd-Cd = 2.6257(5) {\AA}). Like its Group 12 analog Ar'ZnZnAr', DFT calcns. on a model compd. showed that Ar'CdCdAr' had significant p-character in the Cd-Cd σ-bonding HOMO. [on SciFinder(R)]",

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author = "Zhongliang Zhu and Fischer, {Roland C.} and Fettinger, {James C.} and Eric Rivard and Marcin Brynda and Power, {Philip P.}",

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doi = "10.1021/ja066108h",

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journal = "Journal of the American Chemical Society",

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T1 - Synthesis, Structural Characterization, and Spectroscopy of the Cadmium-Cadmium Bonded Molecular Species Ar'CdCdAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2).

AU - Zhu, Zhongliang

AU - Fischer, Roland C.

AU - Fettinger, James C.

AU - Rivard, Eric

AU - Brynda, Marcin

AU - Power, Philip P.

PY - 2006

Y1 - 2006

N2 - The synthesis and 1st structural characterization of a Cd-Cd bonded mol. compd., Ar'CdCdAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2), are reported. Thus, treating Ar'Li with CdI2 in Et2O for 2 days gave 67.2% Ar'CdI, which upon treatment with NaH in THF for 3 days gave 27.6% Ar'CdCdAr'. The existence of the Cd-Cd bond was established by 113Cd NMR spectroscopy and x-ray diffraction (Cd-Cd = 2.6257(5) Å). Like its Group 12 analog Ar'ZnZnAr', DFT calcns. on a model compd. showed that Ar'CdCdAr' had significant p-character in the Cd-Cd σ-bonding HOMO. [on SciFinder(R)]

AB - The synthesis and 1st structural characterization of a Cd-Cd bonded mol. compd., Ar'CdCdAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2), are reported. Thus, treating Ar'Li with CdI2 in Et2O for 2 days gave 67.2% Ar'CdI, which upon treatment with NaH in THF for 3 days gave 27.6% Ar'CdCdAr'. The existence of the Cd-Cd bond was established by 113Cd NMR spectroscopy and x-ray diffraction (Cd-Cd = 2.6257(5) Å). Like its Group 12 analog Ar'ZnZnAr', DFT calcns. on a model compd. showed that Ar'CdCdAr' had significant p-character in the Cd-Cd σ-bonding HOMO. [on SciFinder(R)]

KW - cadmium cadmium bond bulky terphenyl ligand

KW - dinuclear cadmium terphenyl DFT optimized mol structure HOMO

KW - crystal structure dinuclear cadmium bulky terphenyl ligand prepn

KW - mol structure dinuclear cadmium bulky terphenyl ligand

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