Synthesis of Hydrophilic Phosphorus Ligands and Their Application in Aqueous‐Phase Metal‐Catalyzed Reactions

Thomas Schlatzer*, Rolf Breinbauer*

*Korrespondierende/r Autor/in für diese Arbeit

Publikation: Beitrag in einer FachzeitschriftReview eines Fachbereichs (Review article)

Abstract

Transition metal-catalyzed reactions in aqueous media are experiencing a constant increase in interest. In homogenous catalysis the use of water as a solvent offers advantages in cost, safety, the possibility of two-phase catalysis and simplified separation strategies. In the life sciences, transition metal catalysis in aqueous systems enables the ligation or modification of biopolymers in buffer systems or even in their cellular environment. In biocatalysis, aqueous systems allow the simultaneous use of enzymes and transition metal catalysts in cascade reactions. The use of water-soluble phosphine ligands still represents the most reliable and popular strategy for transferring metal catalysts into the aqueous phase. This review summarizes the recent advancements in this field since 2009 and describes current synthetic strategies for the preparation of hydrophilic phosphines and phosphites. In addition, recent applications of transition metal catalysis in aqueous solvents using these hydrophilic ligands are presented. (Figure presented.).

Originalspracheenglisch
Seiten (von - bis)668 – 687
Seitenumfang20
FachzeitschriftAdvanced Synthesis & Catalysis
Jahrgang363
Ausgabenummer3
Frühes Online-Datum11 Dez 2020
DOIs
PublikationsstatusVeröffentlicht - 2 Feb 2021

ASJC Scopus subject areas

  • !!Catalysis
  • Organische Chemie

Fields of Expertise

  • Human- & Biotechnology

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