Syntheses of novel silyl-substituted distannanes.

Roland Fischer; Thorsten Schollmeier; Markus Schuermann; Frank Uhlig

doi:10.1002/aoc.854

Syntheses of novel silyl-substituted distannanes.

Roland Fischer, Thorsten Schollmeier, Markus Schuermann, Frank Uhlig

Institut für Anorganische Chemie (6330)

Publikation: Beitrag in einer Fachzeitschrift › Artikel › Begutachtung

Abstract

Starting from diorganodichlorostannanes, novel bis(triorganosilyl)stannanes and -distannanes were prepd. either by 1-pot reactions via Wurtz-type coupling reactions with Mg or Li and triorganochlorostannanes, or by salt elimination reactions from triorganosilyllithium and diorganodichlorostannanes. A convenient and remarkably straightforward method is the oxidative coupling of K stannides with 1,2-dibromoethane. Isolable intermediates and products were characterized by multinuclear magnetic resonance spectroscopy. To prove the constitution of a distannane, the structure of Ph2MeSiSn(CMe3)2Sn(CMe3)2SiMePh2 was detd. by x-ray crystallog. [on SciFinder(R)]

Originalsprache	englisch
Seiten (von - bis)	523-529
Seitenumfang	7
Fachzeitschrift	Applied Organometallic Chemistry
Jahrgang	19
Ausgabenummer	4
DOIs	https://doi.org/10.1002/aoc.854
Publikationsstatus	Veröffentlicht - 2005

Schlagwörter

distannane stannane silyl substituted prepn
stannane distannane triorganosilyl prepn
crystal structure distannane dimethylphenylsilyl tertiary butyl prepn
mol structure distannane dimethylphenylsilyl tertiary butyl

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10.1002/aoc.854

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abstract = "Starting from diorganodichlorostannanes, novel bis(triorganosilyl)stannanes and -distannanes were prepd. either by 1-pot reactions via Wurtz-type coupling reactions with Mg or Li and triorganochlorostannanes, or by salt elimination reactions from triorganosilyllithium and diorganodichlorostannanes. A convenient and remarkably straightforward method is the oxidative coupling of K stannides with 1,2-dibromoethane. Isolable intermediates and products were characterized by multinuclear magnetic resonance spectroscopy. To prove the constitution of a distannane, the structure of Ph2MeSiSn(CMe3)2Sn(CMe3)2SiMePh2 was detd. by x-ray crystallog. [on SciFinder(R)]",

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doi = "10.1002/aoc.854",

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AU - Fischer, Roland

AU - Schollmeier, Thorsten

AU - Schuermann, Markus

AU - Uhlig, Frank

PY - 2005

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N2 - Starting from diorganodichlorostannanes, novel bis(triorganosilyl)stannanes and -distannanes were prepd. either by 1-pot reactions via Wurtz-type coupling reactions with Mg or Li and triorganochlorostannanes, or by salt elimination reactions from triorganosilyllithium and diorganodichlorostannanes. A convenient and remarkably straightforward method is the oxidative coupling of K stannides with 1,2-dibromoethane. Isolable intermediates and products were characterized by multinuclear magnetic resonance spectroscopy. To prove the constitution of a distannane, the structure of Ph2MeSiSn(CMe3)2Sn(CMe3)2SiMePh2 was detd. by x-ray crystallog. [on SciFinder(R)]

AB - Starting from diorganodichlorostannanes, novel bis(triorganosilyl)stannanes and -distannanes were prepd. either by 1-pot reactions via Wurtz-type coupling reactions with Mg or Li and triorganochlorostannanes, or by salt elimination reactions from triorganosilyllithium and diorganodichlorostannanes. A convenient and remarkably straightforward method is the oxidative coupling of K stannides with 1,2-dibromoethane. Isolable intermediates and products were characterized by multinuclear magnetic resonance spectroscopy. To prove the constitution of a distannane, the structure of Ph2MeSiSn(CMe3)2Sn(CMe3)2SiMePh2 was detd. by x-ray crystallog. [on SciFinder(R)]

KW - distannane stannane silyl substituted prepn

KW - stannane distannane triorganosilyl prepn

KW - crystal structure distannane dimethylphenylsilyl tertiary butyl prepn

KW - mol structure distannane dimethylphenylsilyl tertiary butyl

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