Singlet oxygen generation as a major cause for parasitic reactions during cycling of aprotic lithium-oxygen batteries

Nika Mahne, Bettina Schafzahl, Christian Leypold, Mario Leypold, Sandra Grumm, Anita Leitgeb, Gernot A. Strohmeier, Martin Wilkening, Olivier Fontaine, Denis Kramer, Christian Slugovc, Sergey M. Borisov, Stefan A. Freunberger

Publikation: Beitrag in einer FachzeitschriftArtikelForschungBegutachtung

Abstract

Non-aqueous metal-oxygen batteries depend critically on the reversible formation/decomposition of metal oxides on cycling. Irreversible parasitic reactions cause poor rechargeability, efficiency, and cycle life, and have predominantly been ascribed to the reactivity of reduced oxygen species with cell components. These species, however, cannot fully explain the side reactions. Here we show that singlet oxygen forms at the cathode of a lithium-oxygen cell during discharge and from the onset of charge, and accounts for the majority of parasitic reaction products. The amount increases during discharge, early stages of charge, and charging at higher voltages, and is enhanced by the presence of trace water. Superoxide and peroxide appear to be involved in singlet oxygen generation. Singlet oxygen traps and quenchers can reduce parasitic reactions effectively. Awareness of the highly reactive singlet oxygen in non-aqueous metal-oxygen batteries gives a rationale for future research towards achieving highly reversible cell operation.

Originalspracheenglisch
Aufsatznummer17036
FachzeitschriftNature Energy
Jahrgang2
Ausgabenummer5
DOIs
PublikationsstatusVeröffentlicht - 27 Mär 2017

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Singlet Oxygen
Lithium
Oxygen
Metals
Peroxides
Reaction products
Superoxides
Oxides
Life cycle
Cathodes
Decomposition
Water
Electric potential

ASJC Scopus subject areas

  • !!Energy Engineering and Power Technology
  • !!Fuel Technology
  • !!Renewable Energy, Sustainability and the Environment
  • !!Electronic, Optical and Magnetic Materials

Dies zitieren

Singlet oxygen generation as a major cause for parasitic reactions during cycling of aprotic lithium-oxygen batteries. / Mahne, Nika; Schafzahl, Bettina; Leypold, Christian; Leypold, Mario; Grumm, Sandra; Leitgeb, Anita; Strohmeier, Gernot A.; Wilkening, Martin; Fontaine, Olivier; Kramer, Denis; Slugovc, Christian; Borisov, Sergey M.; Freunberger, Stefan A.

in: Nature Energy, Jahrgang 2, Nr. 5, 17036, 27.03.2017.

Publikation: Beitrag in einer FachzeitschriftArtikelForschungBegutachtung

Mahne, Nika ; Schafzahl, Bettina ; Leypold, Christian ; Leypold, Mario ; Grumm, Sandra ; Leitgeb, Anita ; Strohmeier, Gernot A. ; Wilkening, Martin ; Fontaine, Olivier ; Kramer, Denis ; Slugovc, Christian ; Borisov, Sergey M. ; Freunberger, Stefan A. / Singlet oxygen generation as a major cause for parasitic reactions during cycling of aprotic lithium-oxygen batteries. in: Nature Energy. 2017 ; Jahrgang 2, Nr. 5.
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AU - Leitgeb, Anita

AU - Strohmeier, Gernot A.

AU - Wilkening, Martin

AU - Fontaine, Olivier

AU - Kramer, Denis

AU - Slugovc, Christian

AU - Borisov, Sergey M.

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