TY - JOUR
T1 - Selective Chlorination of Germanium Hydrides
AU - Hafner, Thomas
AU - Torvisco Gomez, Ana
AU - Traxler, Michael
AU - Wolf, Melanie
AU - Uhlig, Frank
PY - 2020/12/31
Y1 - 2020/12/31
N2 - Methods for the selective chlorination of organogermylhydrides are given by the selective functionalization of organogermylhydrides of types R
3GeH, R
2GeH
2 and RGeH
3 (R = alkyl, aryl). The use of trichloroisocyanuric acid (TCCA) allows the direct conversion of Ge-H functions into their monochlorinated derivatives R
2Ge(Cl)H and RGe(Cl)H
2.
AB - Methods for the selective chlorination of organogermylhydrides are given by the selective functionalization of organogermylhydrides of types R
3GeH, R
2GeH
2 and RGeH
3 (R = alkyl, aryl). The use of trichloroisocyanuric acid (TCCA) allows the direct conversion of Ge-H functions into their monochlorinated derivatives R
2Ge(Cl)H and RGe(Cl)H
2.
KW - Inorganic Chemistry
KW - Selective Chlorination
KW - Monochlorination
KW - Selective chlorination
KW - Trichloroisocyanuric acid (TCCA)
KW - Organo(chloro)germylhydrides
KW - Trifluoromethylsulfonic acid
UR - http://www.scopus.com/inward/record.url?scp=85096692815&partnerID=8YFLogxK
U2 - 10.1002/zaac.202000318
DO - 10.1002/zaac.202000318
M3 - Article
SN - 1521-3749
VL - 646
SP - 1876
EP - 1881
JO - Zeitschrift für Anorganische und Allgemeine Chemie
JF - Zeitschrift für Anorganische und Allgemeine Chemie
IS - 23-24
M1 - 10.1002/zaac.202000318
ER -