Redistribution reaction on a six-fold coordinated Sn(IV) atom and reactions towards axially unsymmetric substituted Sn(IV) porphyrins

Doris Martina Grössl (Co-Herausgeber), Stefan Stadlbauer*, Roland Fischer (Co-Herausgeber), Frank Uhlig, Nicola Demitri (Co-Herausgeber)

*Korrespondierende/r Autor/in für diese Arbeit

Publikation: Beitrag in einer FachzeitschriftArtikel

Abstract

Investigations of the Kocheshkov redistribution reaction were performed on the six fold coordinated tin(IV) atom using the axially coordinated Sn(IV) meso-tetra-phenylporphyrin system with axially trans di-chloro and trans di-acetylido substituted derivatives. The immobile four dentate porphyrin ligand enables the detailed investigation of these typically complex reaction systems on higher coordinated tin(IV) species. The thermally activated reaction displays an equilibrium. Further on, a series of axial unsymmetrically substituted Sn(IV) porphyrins are selectively synthesized and described.

Originalspracheenglisch
Aufsatznummer121470
FachzeitschriftJournal of Organometallic Chemistry
Jahrgang925
DOIs
PublikationsstatusVeröffentlicht - 15 Okt 2020

ASJC Scopus subject areas

  • !!Materials Chemistry
  • !!Biochemistry
  • Anorganische Chemie
  • !!Physical and Theoretical Chemistry
  • Organische Chemie

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