Probing the first steps of photoinduced free radical polymerization at water-oil interfaces

Denisa Darvasiová, Zuzana Barberiková, Anna Eibel, Max Schmallegger, Georg Gescheidt, Michal Zalibera, Dmytro Neshchadin

Publikation: Beitrag in einer FachzeitschriftArtikelForschungBegutachtung

Abstract

Phosphanoyl radicals, produced by α-photocleavage of exclusively octane-soluble acylphosphane oxides, rapidly react with both water- and octane-soluble monomers in water-in-octane microemulsions. The presented mechanistic insights open the possibility for the tailored construction of photo-generated copolymers comprising polar and non-polar blocks at the same time.

Originalspracheenglisch
Seiten (von - bis)6943-6947
Seitenumfang5
FachzeitschriftPolymer Chemistry
Jahrgang8
Ausgabenummer45
DOIs
PublikationsstatusVeröffentlicht - 7 Dez 2017

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Free radical polymerization
Polymerization
Free Radicals
Oils
Water
Microemulsions
Copolymers
Monomers
Oxides
octane

ASJC Scopus subject areas

  • Bioengineering
  • !!Biochemistry
  • !!Polymers and Plastics
  • Organische Chemie

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Probing the first steps of photoinduced free radical polymerization at water-oil interfaces. / Darvasiová, Denisa; Barberiková, Zuzana; Eibel, Anna; Schmallegger, Max; Gescheidt, Georg; Zalibera, Michal; Neshchadin, Dmytro.

in: Polymer Chemistry, Jahrgang 8, Nr. 45, 07.12.2017, S. 6943-6947.

Publikation: Beitrag in einer FachzeitschriftArtikelForschungBegutachtung

Darvasiová, Denisa ; Barberiková, Zuzana ; Eibel, Anna ; Schmallegger, Max ; Gescheidt, Georg ; Zalibera, Michal ; Neshchadin, Dmytro. / Probing the first steps of photoinduced free radical polymerization at water-oil interfaces. in: Polymer Chemistry. 2017 ; Jahrgang 8, Nr. 45. S. 6943-6947.
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