TY - JOUR
T1 - Postsynthetic Metalated MOFs as Atomically Dispersed Catalysts for Hydroformylation Reactions
AU - Tang, Panjuan
AU - Paganelli, Stefano
AU - Carraro, Francesco
AU - Blanco, Matias
AU - Riccò, Raffaele
AU - Marega, Carla
AU - Badocco, Denis
AU - Pastore, Paolo
AU - Doonan, Christian J.
AU - Agnoli, Stefano
PY - 2020/12/9
Y1 - 2020/12/9
N2 - A manganese-based metal-organic framework with dipyrazole ligands has been metalated with atomically dispersed Rh and Co species and used as a catalyst for the hydroformylation of styrene. The Rh-based materials exhibited excellent conversion at 80 °C with complete chemoselectivity, high selectivity for the branched aldehyde, high recyclability, and negligible metal leaching.
AB - A manganese-based metal-organic framework with dipyrazole ligands has been metalated with atomically dispersed Rh and Co species and used as a catalyst for the hydroformylation of styrene. The Rh-based materials exhibited excellent conversion at 80 °C with complete chemoselectivity, high selectivity for the branched aldehyde, high recyclability, and negligible metal leaching.
KW - heterogeneous catalysis
KW - hydroformylation of olefins
KW - metal-organic frameworks
KW - rhodium coordination compounds
KW - single-atom catalysts
UR - http://www.scopus.com/inward/record.url?scp=85097808684&partnerID=8YFLogxK
U2 - 10.1021/acsami.0c17073
DO - 10.1021/acsami.0c17073
M3 - Article
C2 - 33232111
AN - SCOPUS:85097808684
SN - 1944-8244
VL - 12
SP - 54798
EP - 54805
JO - ACS Applied Materials and Interfaces
JF - ACS Applied Materials and Interfaces
IS - 49
ER -